Citation: MA Xiaohong, WANG Qiang, LI Xiaoping, TANG Jun, ZHANG Zhengfang. Determination of the solubility parameter of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate by inverse gas chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(11): 1192-1198. doi: 10.3724/SP.J.1123.2015.04041 shu

Determination of the solubility parameter of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate by inverse gas chromatography

1.
Center for Physical and Chemical Analysis, Xinjiang University, Urumqi 830046, China

Corresponding author: WANG Qiang,
Received Date: 22 April 2015

Fund Project: National Natural Science Foundation of China (Grant No. 21366029). (Grant No. 21366029)

Thermodynamic properties of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM]BF₄) were determined via inverse gas chromatography (IGC). Two groups of solvents with different chemical natures and polarities were used to obtain information about [BMIM]BF₄-solvent interactions. The specific retention volume, molar heat of sorption, weight fraction activity coefficient, Flory-Huggins interaction parameter as well as solubility parameter were also determined in a temperature range of 333-373 K. The results showed that the selected solvents n-C₁₀ to n-C₁₂, carbon tetrachloride, cyclohexane and toluene were poor solvents for [BMIM]BF₄, while dichloromethane, acetone, chloroform, methyl acetate, ethanol and methanol were favorite solvents for [BMIM]BF₄. In addition, the solubility parameter of [BMIM]BF₄ was determined as 23.39 (J/cm³)^0.5 by the extrapolation at 298 K. The experiment proved that IGC was a simple and accurate method to obtain the thermodynamic properties of ionic liquids. This study could be used as a reference to the application and research of the ionic liquids.
- inverse gas chromatography (IGC),
- ionic liquid (IL),
- Flory-Huggins interaction parameter,
- solubility parameter
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