Citation: ZOU Chunmiao, ZHANG Xiaodong, YU Hong, GUAN Chao, WANG Miaoyu. Ion-pair chromatography-indirect ultraviolet detection for determination of tetraethyl ammonium using a monolithic column and a packed column[J]. Chinese Journal of Chromatography, ;2015, 33(7): 759-764. doi: 10.3724/SP.J.1123.2015.03043 shu

Ion-pair chromatography-indirect ultraviolet detection for determination of tetraethyl ammonium using a monolithic column and a packed column

1.
1. College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China;

Corresponding author: YU Hong,
Received Date: 31 March 2015

Fund Project: 黑龙江省自然科学基金项目(B201307) (B201307)哈尔滨师范大学硕士研究生创新科研项目(HSDSSCX2014-22). (HSDSSCX2014-22)

Two methods were developed for the determination of tetraethyl ammonium by ion-pair chromatography-indirect ultraviolet detection using a monolithic column and a packed column with ionic liquid as additive in mobile phase. Chromatographic separations were performed on a monolithic column and a packed column both on reversed phase using imidazolium ionic liquid aqueous solution-ion-pair reagent-organic solvent as mobile phase. The effects of the background ultraviolet absorption reagent, detection wavelength, ion-pair reagent, organic solvent, column temperature and flow rate on the determination of tetraethyl ammonium were investigated. The difference between the two chromatographic columns was compared and the retention rules were discussed. Under the optimized chromatographic conditions, for tetraethyl ammonium on monolithic column and packed column, the retention times were 2.40 and 3.02 min; the detection limits (S/N=3), 0.04 and 0.07 mg/L; the RSDs (n=5) for peak areas, 0.16% and 0.11%; and the RSDs (n=5) for retention times, 0.02% and 0.01%, respectively. The two methods have been successfully applied to the determination of tetraethyl ammonium ionic liquids synthesized by laboratory. The recoveries of the tetraethyl ammonium after spiking were 98.2% and 99.1%, respectively. The two methods can meet the requirements for the quantitative analysis of tetraethyl ammonium.
- ion-pair chromatography,
- indirect ultraviolet detection,
- tetraethyl ammonium,
- imidazolium ionic liquids,
- monolithic column,
- packed column
1. [1]
  [1] Chen H Q, Li G F, He G Y, et al. Fine Chemicals (陈海群, 李根发, 何光裕, 等. 精细化工), 2009, 26(9): 870
2. [2]
  [2] Zhao B, Chen D J, Li Y L, et al. Journal of Molecular Catalysis (赵彬, 陈殿军, 李永路, 等. 分子催化), 2008, 22(6): 487
3. [3]
  [3] Li X X. Journal of Shanxi Agricultural University: Natural Science Edition (李晓旭. 山西农业大学学报: 自然科学版), 2007, 27(1): 99
4. [4]
  [4] Jia L L, Zhang W F. Chinese Journal of Disinfection (贾丽丽, 张文福. 中国消毒学杂志), 2008, 25(1): 64
5. [5]
  [5] Lin X Y, Hu H P, Liu H. Journal of Changsha University of Electric Power (林向阳, 胡慧萍, 刘辉. 长沙电力学院学报), 2004, 19(3): 91
6. [6]
  [6] Zhuang H R. Environmental Monitoring in China (庄会荣. 中国环境监测), 2004, 20(5): 25
7. [7]
  [7] Li M R, Sun F L, Guo C H, et al. China Surfactant Detergent & Cosmetics (李美蓉, 孙方龙, 郭长会, 等. 日用化学工业), 2012, 42(5): 383
8. [8]
  [8] Liu J Q, Zhai Z L, Zhang X B, et al. Chinese Journal of Disinfection (刘吉起, 翟志雷, 张向兵, 等. 中国消毒学杂志), 2012, 29(1): 51
9. [9]
  [9] Jin Y, Chen Z F. Chemical World (金燕, 陈志峰. 化学世界), 1999(5): 266
10. [10]
  [10] Lu S, Ji R. Industrial Water Treatment (卢姝, 纪然. 工业水处理), 2011, 31(9): 76
11. [11]
  [11] Yu X H, Hao L H, Liu K Y, et al. Chinese Journal of Veterinary Drug (于晓辉, 郝利华, 柳焜耀, 等. 中国兽药杂志), 2012, 46(2): 33
12. [12]
  [12] He S M, Liu Y Q, Han S T, et al. Chinese Journal of Spectroscopy Laboratory (何书美, 刘彦钦, 韩士田, 等. 光谱实验室), 2000, 17(1): 61
13. [13]
  [13] Liu Z J, Chen W D, Zhu F Y, et al. Journal of Analytical Science (刘壮峻, 陈卫东, 朱凤英, 等. 分析科学学报), 2006, 22(3): 312
14. [14]
  [14] Gao X X, Qi J, Zhao M X, et al. Spectroscopy and Spectral Analysis (高秀香, 齐剑, 赵梅仙, 等. 光谱学与光谱分析), 2008, 28(6): 1420
15. [15]
  [15] Bai L G, Niu W J, Yang G L. Chinese Journal of Chromatography (白立改, 牛文敬, 杨更亮. 色谱), 2013, 31(4): 303
16. [16]
  [16] Liu Y C, Liu Z. Chinese Journal of Chromatography (刘云春, 刘震. 色谱), 2013, 31(4): 348
17. [17]
  [17] Li J, Zhu Y. Chinese Journal of Analytical Chemistry (李晶, 朱岩. 分析化学), 2013, 41(3): 400
18. [18]
  [18] Ma Y J, Li M, Yu H, et al. Chinese Chemical Letters, 2013, 24(12): 1067
19. [19]
  [19] Dou A B, Zou C J, Shan Y H, et al. Chinese Journal of Chromatography (窦阿波, 邹存杰, 单圆鸿, 等. 色谱), 2014, 32(5): 447
20. [20]
  [20] Kuang Y Y, Wang Y, Gu X, et al. Chinese Journal of Chromatography (况媛媛, 王彦, 谷雪, 等. 色谱), 2014, 32(4): 388
21. [21]
  [21] Liu H Y, Ding W H. J Chromatogr A, 2004, 1025(2): 303
22. [22]
  [22] Zhou X J, Shi Y P. Chinese Journal of Chromatography (周贤婧, 师彦平. 色谱), 2013, 31(7): 661
23. [23]
  [23] Sun Y M, Yu H. Chinese Journal of Chromatography (孙艺梦, 于泓. 色谱), 2013, 31(10): 969
24. [24]
  [24] An Y, Yu H, Zou C M. Chinese Journal of Analytical Chemistry (安莹, 于泓, 邹春苗. 分析化学), 2013, 41(7): 1057
25. [25]
  [25] Zheng X R, Ma Y J, Yu H. Journal of Instrumental Analysis (郑秀荣, 马亚杰, 于泓. 分析测试学报), 2014, 33(9): 1026
26. [26]
  [26] Wang M Y, Yu H, Li P, et al. Chinese Journal of Chromatography (王淼煜, 于泓, 李萍, 等. 色谱), 2014, 32(7): 773
27. [27]
  [27] Ruiz-Angel M J, Berthod A. J Chromatogr A, 2006, 1113 (1/2): 101
28. [28]
  [28] Yang L L, Zhang X Z, Tian H F. Chinese Journal of Inorganic Analytical Chemistry (杨兰玲, 张习志, 田海峰. 中国无机分析化学), 2012, 28(2): 43
1. [1]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
2. [2]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
3. [3]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
4. [4]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
5. [5]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
6. [6]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
7. [7]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
8. [8]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
9. [9]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
10. [10]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
11. [11]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
12. [12]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
13. [13]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
14. [14]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
15. [15]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
16. [16]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
17. [17]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
18. [18]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(309)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142