Citation: HAO Weiqiang, WANG Leijun, WU Shun, YUE Bangyi, CHEN Qiang, ZHANG Peipei. Analysis of alkaline CuO degradation products of acid detergent fiber from tobacco leaves by using liquid chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(7): 777-782. doi: 10.3724/SP.J.1123.2015.01043 shu

Analysis of alkaline CuO degradation products of acid detergent fiber from tobacco leaves by using liquid chromatography

HAO Weiqiang ^1,2,, ,
WANG Leijun ¹ ,
WU Shun ² ,
YUE Bangyi ² ,
CHEN Qiang ² ,
ZHANG Peipei ²

1.
1. Key Laboratory of Cigarette Smoke Research, Shanghai Tobacco Group Co., Ltd., China National Tobacco Corporation (CNTC), Shanghai 200082, China;

Corresponding author: HAO Weiqiang,
Received Date: 29 January 2015

Fund Project: 烟草行业卷烟烟气重点实验室开放研究基金项目(SZBCW201300555) (SZBCW201300555)江苏省自然科学基金项目(BK20141163). (BK20141163)

The acid detergent fiber (ADF) from tobacco leaves was obtained by treating the sample with petroleum ether-ethanol (6 : 4, v/v), 30 g/L sodium dodecylsulfate and 0.5 mol/L sulphuric acid containing 20 g/L hexadecyl trimethyl ammonium bromide successively. The ADF was degraded by the alkaline CuO oxidation procedure. In this work, six samples of ADF degradation products from tobacco leaves were prepared. The samples were analyzed by using gradient liquid chromatography (LC) where an Ultimate XB C18 column was used as stationary phase, with a mixture of methanol and water as mobile phase, at a column temperature of 35 ℃ and a flow rate of 0.8 mL/min. Dual wavelengths of 280 nm and 320 nm were chosen for the detection. It was found that there were four characteristic peaks for the ADF degradation products. By taking these peaks as research object, the optimum time for the degradation was found to be 5 h and the sample solution could be kept stable within 7 days. The established method may provide a new approach for the studies of the differences between lignin composition in different tobacco leaves and the relationship between lignin content and the smoking quality of tobacco leaves.
- liquid chromatography (LC),
- acid detergent fiber (ADF),
- alkaline CuO degradation,
- lignin,
- tobacco leaves
1. [1]
  [1] Liu C K, Cai J, Yang J, et al. Guangdong Agricultural Sciences (刘春奎, 蔡佳, 杨靖, 等. 广东农业科学), 2012(12): 33
2. [2]
  [2] Zhang Q, Dong G F, Huang W, et al. Tobacco Science & Technology (张强, 董高峰, 黄韡, 等. 烟草科技), 2014(3): 76
3. [3]
  [3] Cao S Y, Hu W R, Fan L. Polymer Bulletin (曹双瑜, 胡文冉, 范玲. 高分子通报), 2012(3): 8
4. [4]
  [4] Vanholme R, Morreel K, Ralph J, et al. Curr Opin Plant Biol, 2008, 11(3): 278
5. [5]
  [5] Li H T, Yao K, Jia D Y, et al. Leather Science and Engineering (李海涛, 姚开, 贾冬英, 等. 皮革科学与工程), 2011, 21(2): 31
6. [6]
  [6] Goff B M, Murphy P T, Moore K J. J Sci Food Agric, 2012, 92(4): 751
7. [7]
  [7] Yang B, Yin Y, Zhang H B, et al. Acta Tabacaria Sinica (杨斌, 殷引, 张浩博, 等. 中国烟草学报), 2012, 18(3): 10
8. [8]
  [8] Guo X Y, Dai Y H, Guo Z M, et al. Tobacco Science & Technology (郭小义, 戴云辉, 郭紫明, 等. 烟草科技), 2009(1): 43
9. [9]
  [9] Fukushima R S, Hatfield R D. J Agric Food Chem, 2004, 52(12): 3713
10. [10]
  [10] Cui P, Fang H X, Wu Q L, et al. Chinese Journal of Chromatography (崔朋, 方红霞, 吴强林, 等. 色谱), 2015, 33(3): 314
11. [11]
  [11] Goni M A, Montgomery S. Anal Chem, 2000, 72(14): 3116
12. [12]
  [12] Yu Y C, Li K L, Ma Y C, et al. Chinese Journal of Chromatography (于雅晨, 李坤兰, 马英冲, 等. 色谱), 2013, 31(2): 143
13. [13]
  [13] Hedges J I, Ertel J R. Anal Chem, 1982, 54(2): 174
14. [14]
  [14] Bahri H, Dignac M F, Rumpel C, et al. Soil Biol Biochem, 2006, 38(7): 1977
15. [15]
  [15] Hautala K, Peuravuori J, Pihlaja K. Chemosphere, 1997, 35(4): 809
16. [16]
  [16] Liu N, Zhang W, He H B, et al. Analytical Instrumentation (刘宁, 张威, 何红波, 等. 分析仪器), 2010(6): 30
17. [17]
  [17] Steinberg S, Venkatesan M I, Kaplan I R. J Chromatogr, 1984, 298: 427
18. [18]
  [18] GB 54136-2010
19. [19]
  [19] Sun R, Lawther J M, Banks W B. Ind Crop Prod, 1995, 4(4): 241
20. [20]
  [20] van der Hage E R E, Boon J J. J Chromatogr A, 1996, 736: 61
1. [1]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
5. [5]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
6. [6]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
7. [7]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
8. [8]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
9. [9]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
10. [10]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
11. [11]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
12. [12]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
13. [13]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
14. [14]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
15. [15]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
16. [16]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
17. [17]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
18. [18]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
19. [19]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
20. [20]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(426)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142