Citation: YAO Weixuan, YING Jianbo, ZHANG Suling, ZHANG Chunxiao, WANG Haidong, CAI Guodong. Preparation of multi-walled carbon nanotubes decorated with Fe₃O₄ nanoparticles for determination of trace pyrethroid pesticides in water and honey samples[J]. Chinese Journal of Chromatography, ;2015, 33(4): 342-347. doi: 10.3724/SP.J.1123.2014.11029 shu

Preparation of multi-walled carbon nanotubes decorated with Fe₃O₄ nanoparticles for determination of trace pyrethroid pesticides in water and honey samples

1.
1. Department of Criminal Science and Technology, Zhejiang Police College, Hangzhou 310053, China;

Corresponding author: YAO Weixuan, ZHANG Suling,
Received Date: 26 November 2014
Available Online: 20 January 2015
Fund Project: 国家自然科学基金项目(21305026) (21305026)浙江省自然科学基金项目(LQ13B050005) (LQ13B050005)浙江省教育厅科研项目(Y201328959) (Y201328959)公安部科技专项项目(2013YYCXZJST079). (2013YYCXZJST079)

A magnetic carbon nanotube hybrid material was prepared using a chemical co-precipitation method. The Fe₃O₄ nanoparticles were enclosed onto the surface of the acid multi-walled carbon nanotubes (AMWNTs), and they were identified as Fe₃O₄/AMWNTs composites. This hybrid materials displayed typical superparamagnetic behavior, good dispersibility, and good adsorption capacity for pyrethroid pesticides. A magnetic solid-phase microextraction (MSPE) procedure based on Fe₃O₄/AMWNTs composites, combined with gas chromatography, was developed for the quantification of six pyrethroid pesticides in water and honey samples. Several important parameters affecting the extraction efficiency for six pyrethroid pesticides were optimized in sequential order, including ionic strength, extraction time and desorption time. Under the optimized conditions, this method showed wide linearity ranging from 0.5 μg/L to 50 μg/L with correlation coefficients (R²) higher than 0.990. The limits of detection (LODs) ranged from 0.07 μg/L to 0.20 μg/L at a singal-to-noise ratio of 3. The relative standard deviations (RSDs) ranged from 3.8% to 8.1%. Satisfactory recoveries (>78.4%) were obtained for the simultaneous analysis of the six pyrethroid pesticide residues in river water, fishpond water and two honey samples. This method is sensitive and simple. It can meet the actual requirement for the analysis of trace analytes from environmental water and honey samples.
- carbon nanotube,
- magnetic nanoparticles,
- magnetic solid-phase extraction,
- gas chromatography (GC),
- pyrethroid pesticides,
- water,
- honey
1. [1]
  [1] Zhang X H, Yan L S, Tang M L, et al. Journal of Wuhan Institute of Technology (张细华, 颜流水, 汤麦莲, 等. 武汉工程大学学报), 2011, 33(11): 35
2. [2]
  [2] Ma Z M. Fujian Analysis & Testing (马志梅. 福建分析测试), 2007, 16(3): 61
3. [3]
  [3] Shi X Z, Liu J H, Sun A L, et al. J Chromatogr A, 2012, 1227: 60
4. [4]
  [4] de Souza Pinheiro A, de Rocha G O, de Andrade J B. Microchem J, 2011, 99: 303
5. [5]
  [5] Román I S, Alonso M L, Bartolomé L, et al. Talanta, 2012, 100: 246
6. [6]
  [6] Chen J M, Zou J, Zeng J B, et al. Anal Chim Acta, 2010, 678: 44
7. [7]
  [7] Li H P, Lin C H, Jen J F. Talanta, 2009, 79: 466
8. [8]
  [8] Jia Q, Qiu J, Li Y, et al. Quality and Safety of Agro-products (贾琪, 邱静, 李熠, 等. 农产品质量与安全), 2014(4): 47
9. [9]
  [9] Wu H, Yu L S, Tan H R, et al. Journal of Anhui Agricultural University (吴虹, 余林生, 檀华蓉, 等. 安徽农业大学学报), 2013, 40(2): 146
10. [10]
  [10] Ren H B. Agrochemicals (任红波. 农药), 2007, 46(2): 125
11. [11]
  [11] Wang J X, Wang Y Q, Zhao Y, et al. Food Research and Development (王吉祥, 王亚琴, 赵昱, 等. 食品研究与开发), 2013, 34(15): 71
12. [12]
  [12] Rissatoa S R, Galhianea M S, Knollb F, et al. J Chromatogr A, 2004, 1048: 153
13. [13]
  [13] Zhang J, Gao H, Peng B, et al. J Chromatogr A, 2011, 1218: 6621
14. [14]
  [14] Ding L, Wang H. Chinese Journal of Chromatography (丁兰, 王慧. 色谱), 2013, 31(2): 93
15. [15]
  [15] He S W, Huang Z P, Zhu Y. Chinese Journal of Chromatography (何世伟, 黄忠平, 朱岩. 色谱), 2013, 31(12): 1146
16. [16]
  [16] Pan S D, Chen X H, Zhao Y G, et al. Chemistry (潘胜东, 陈晓红, 赵永纲, 等. 化学通报), 2013, 76(12): 1067
17. [17]
  [17] Luo Y B, Yu Q W, Yuan B F, et al. Talanta, 2012, 90: 123
18. [18]
  [18] Zhang H F, Shi Y P. Anal Chim Acta, 2012, 724: 54
19. [19]
  [19] Morales-Cid G, Fekete A, Simonet B M, et al. Anal Chem, 2010, 82: 2743
20. [20]
  [20] Hu C, Chen B, He M, et al. J Chromatogr A, 2013, 1300: 165
21. [21]
  [21] Zhang S L, Du Z, Li G. Anal Chem, 2011, 83: 7531
22. [22]
  [22] Hu X B, Liu B Z, Deng Y H, et al. Appl Catal B Environ, 2011, 107: 274
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
4. [4]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
5. [5]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
6. [6]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
7. [7]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
8. [8]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
9. [9]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
10. [10]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
11. [11]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
12. [12]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
13. [13]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
14. [14]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
15. [15]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
16. [16]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
18. [18]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(337)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of multi-walled carbon nanotubes decorated with Fe3O4 nanoparticles for determination of trace pyrethroid pesticides in water and honey samples

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of multi-walled carbon nanotubes decorated with Fe₃O₄ nanoparticles for determination of trace pyrethroid pesticides in water and honey samples