Citation: ZHU Feng. Determination of di(hydrogenated tallow alkyl) dimethyl ammonium compounds in textile auxiliaries by ultra-high performance liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(1): 68-74. doi: 10.3724/SP.J.1123.2014.09023 shu

Determination of di(hydrogenated tallow alkyl) dimethyl ammonium compounds in textile auxiliaries by ultra-high performance liquid chromatography-tandem mass spectrometry

ZHU Feng ^1,2,,

1.
1. National Textile and Garment Quality Supervision Testing Center (Fujian), Fuzhou 350026, China;

Corresponding author: ZHU Feng,
Received Date: 17 September 2014
Available Online: 29 October 2014
Fund Project: 福建省质量技术监督局科技项目(FJQI2012003). (FJQI2012003)

A method has been developed for the determination of di(hydrogenated tallow alkyl) dimethyl ammonium compounds (DHTDMAC) in textile auxiliaries by ultra-high performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The samples were extracted and diluted with acidified methanol by 5%(v/v) formic acid under ultrasonic assistance. The separation was performed on an Eclipse Plus C18 column (50 mm×2.1 mm, 1.8 μm) using 0.1%(v/v) formic acid solution and methanol as the mobile phases. Identification and quantification were achieved by UPLC-MS/MS with electrospray ionization (ESI) source in positive ion mode and multiple reaction monitoring (MRM) mode. The results indicated that the calibration curve of DHTDMAC showed good linear relationship between peak area and mass concentration in the range of 10-280 μg/L with the correlation coefficient (r²) of 0.9991. The limit of detection (LOD, S/N=3) and the limit of quantification (LOQ, S/N=10) of this method were 3 mg/kg and 10 mg/kg, respectively. The average recoveries from three typical textile auxiliary matrices including dispersant, anti-static agent and fabric softener, at three spiked levels were in the range of 97.2%-108.3% with the relative standard deviations (RSDs) of 1.5%-4.6%. The method is sensitive, accurate, simple and effective for the analysis of DHTDMAC in textile auxiliaries.
1. [1]
  [1] Gerike P, Klotz H, Kooijman J G A, et al. Water Res, 1994, 28(1): 147
2. [2]
  [2] Breen D, Horner J M, Bartle K D, et al. Water Res, 1996, 30(2): 476
3. [3]
  [3] Institute for Health and Consumer Protection (IHCP). European Union Risk Assessment Report: Dimethyldioctadecylammonium Chloride. [2012-06-06]. http://echa.europa.eu/documents/10162/46f2f114-12ff-4af4-8da7-72148b6a202e
4. [4]
  [4] European Chemicals Agency (ECHA). Quaternary Ammonium Compounds, Bis(hydrogenated tallow alkyl)dimethyl, chlorides. [2013-12-16]. http://apps.echa.europa.eu/registered/data/dossiers/DISS-9ea9dcb9-7848-3271-e044-00144f- 67d031/AGGR-fab45abb-836b-4a05-a42e-d0ec391c1cae_DISS- 9ea9dcb9-7848-3271-e044-00144f67d031.html#L-0b8f67c7-138a-421d-9947-f56bf4f435dd
5. [5]
  [5] Levinson M I. J Surfact Deterg, 1999, 2(2): 223
6. [6]
  [6] Bernd W, Jurgen F. Rev Pro Color, 2002, 32(1): 118
7. [7]
  [7] Zhu F, Wei M, Yang Y R, et al. Journal of Chinese Mass Spectrometry Society (朱峰, 卫敏, 杨瑜榕, 等. 质谱学报), 2014, 35(6): 563
8. [8]
  [8] Comber S D W, Rule K L, Conrad A U, et al. Environ Pollut, 2008, 153(1): 184
9. [9]
  [9] García M T, Campos E, Sánchez-Leal J, et al. Chemosphere, 2000, 41(5): 705
10. [10]
  [10] Sun H F, Takata A, Hata N, et al. J Environ Monit, 2003, 5(6): 891
11. [11]
  [11] 2002/371/EC
12. [12]
  [12] The International Working Group on Global Organic Textile Standard. Global Organic Textile Standard (GOTS), 2011
13. [13]
  [13] Norwegian Pollution Control Authority. Draft of New Chapter Concerning Consumer Products in the Norwegian Product Regulations, 2007
14. [14]
  [14] Li X L, Brownawell B J. Environ Sci Technol, 2010, 44(19): 7561
15. [15]
  [15] Martínez-Carballo E, Sitka A, Gonzáez-Barreiro C, et al. Environ Pollut, 2007, 146(2): 543
16. [16]
  [16] Li X L, Brownawell B J. Anal Chem, 2009, 81(19): 7926
17. [17]
  [17] Michael R, Thilo B, Jurgen F, et al. Anal Chem, 1999, 71(23): 5362
18. [18]
  [18] Fernandez P, Alder A C, Suter M J F, et al. Anal Chem, 1996, 68(5): 921
19. [19]
  [19] Martínez-Carballo E, Gonzáez-Barreiro C, Sitka A, et al. Environ Pollut, 2007, 145(2): 489
20. [20]
  [20] Voorde A, Lorgeoux C, Gromaire M C, et al. Environ Pollut, 2012, 164: 150
21. [21]
  [21] Nitschke L, Miiller R, Metzner G, et al. Fresenius J Anal Chem, 1992, 342(9): 711
22. [22]
  [22] Wee V T, Kennedy J M. Anal Chem, 1982, 54(9): 1631
23. [23]
  [23] Li Q Z, Zhou M H, Yue D L, et al. Journal of Instrumental Analysis (李全忠, 周明辉, 岳大磊, 等. 分析测试学报), 2011, 30(12): 1444
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
3. [3]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
4. [4]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
7. [7]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
8. [8]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
9. [9]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
10. [10]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
11. [11]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
12. [12]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
13. [13]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
14. [14]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
15. [15]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
16. [16]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
17. [17]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
18. [18]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
19. [19]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
20. [20]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(174)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142