Citation: YOU Feiming. Simultaneous determination of six components in hair dyes by ultra performance liquid chromatographytandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(1): 17-21. doi: 10.3724/SP.J.1123.2014.09009 shu

Simultaneous determination of six components in hair dyes by ultra performance liquid chromatographytandem mass spectrometry

YOU Feiming ^,

1.
National Center of Processed Foods Quality Supervision and Inspection, Fujian Inspection and Research Institute for Product Quality, Fuzhou 350002, China

Corresponding author: YOU Feiming,
Received Date: 5 September 2014
Available Online: 3 November 2014
Fund Project: 国家质检总局公益性行业科研专项(2012104013-5). (2012104013-5)

A sensitive method was developed for the simultaneous determination of six components which included 4,4'-diaminodiphenylamine sulfate hydrate and 2,4-diaminophenol sulfate, etc. in hair dyes by ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). After extracted by water through ultrasonic extraction, the samples were analyzed by UPLC-MS/MS. The separation was performed on a Waters BEH-C₁₈ column (100 mm×2.1 mm, 1.7 μm) with gradient elution of 10 mmol/L ammonium acetate and acetonitrile. The electrospray ionization (ESI) source in positive ion mode was used for the analysis of the six components in the multiple reaction monitoring (MRM) mode. The results showed good linear relationships with all the correlation coefficients (R²) more than 0.99. The limits of detection (LODs, S/N=3) for the six components were in the range of 0.26-4.6 mg/kg. The average recoveries of the six components in the spiked samples were in the range of 83.0%-92.2% with the relative standard deviations (RSDs, n=6) of 5.4%-11.2%. The precision, accuracy, mean recoveries and the matrix effects satisfied the requirements of cosmetic sample measurement. The proposed method has been applied to the determination of six dyes in actual samples. This method is simple, accurate and effective for the simultaneous determination of the six components in hair dyes.
- ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS),
- dyes,
- hair dyes
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沈阳化工大学材料科学与工程学院沈阳 110142