Citation: ZHOU Liangqin, FU Dayou, YUAN Dong, FAN Jinlong, TAN Wenyuan. Surface properties of ZnMgAl hydrotalcite-like compounds by inverse gas chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(1): 96-100. doi: 10.3724/SP.J.1123.2014.07032 shu

Surface properties of ZnMgAl hydrotalcite-like compounds by inverse gas chromatography

1.
1. Analysis and Testing, Sichuan University of Science & Engineering, Zigong 643000, China;

Corresponding author: YUAN Dong,
Received Date: 21 July 2014
Available Online: 2 September 2014
Fund Project: 四川省科技厅基础研究计划项目(2013JY0081) (2013JY0081)2014年度绿色催化四川省高校重点实验室项目(LYJ1405) (LYJ1405)四川理工学院2012培养项目(2012PY02). (2012PY02)

The structure of ZnMgAl hydrotalcite-like compounds (ZnMgAl-HTLC) prepared by hydrothermal synthesis was studied by X-ray diffraction (XRD). With a series of polar and non-polar molecules as probes, inverse gas chromatography (IGC) was used to measure the surface properties of ZnMgAl-HTLC. It was found that the XRD pattern of ZnMgAl-HTLC was narrow, sharp and high. The results showed that ZnMgAl-HTLC with a higher purity was obtained by hydrothermal synthesis. The surface adsorption free energy was less than zero. The surface dispersive free energy was 6.02mJ/m². The acid-base interaction free energy was 5.33 kJ/mol. The adsorption enthalpy was 43.6 kJ/mol, and the adsorption entropy was 0.15 kJ/mol. The IGC method is significant in the study of the surface properties of ZnMgAl-HTLC.
- inverse gas chromatography (IGC),
- ZnMgAl hydrotalcite-like compounds (ZnMgAl-HTLC),
- surface properties
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沈阳化工大学材料科学与工程学院沈阳 110142