Citation: LIANG Xixi, CHEN Chuang, WANG Weiguo, LI Haiyang. Detection of 1,4-dioxane in water by membrane extraction-gas chromatography/differential mobility spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(8): 837-842. doi: 10.3724/SP.J.1123.2014.04035 shu

Detection of 1,4-dioxane in water by membrane extraction-gas chromatography/differential mobility spectrometry

LIANG Xixi ^1,2 ,
CHEN Chuang ¹ ,
WANG Weiguo ¹ ,
LI Haiyang ^1,,

1.
1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;

Corresponding author: LI Haiyang,
Received Date: 23 April 2014
Available Online: 9 June 2014
Fund Project: 国家重大科学仪器设备开发专项(2013YQ09070302) (2013YQ09070302)国家自然科学基金项目(21177124,21077101) (21177124,21077101)国民核生化灾害防护国家重点实验室课题(SKLNBC2012-08K). (SKLNBC2012-08K)

The method of detecting trace 1,4-dioxane in water using membrane extraction coupled with gas chromatography/differential mobility spectrometry (GC/DMS) was developed. The parameters including radio frequency voltage, sampling flow rate, permeation time and trapping time were optimized to 1000 V, 50 mL/min, 30 min and 150 s, respectively. The linear range for dioxane was obtained from 2.0 μg/L to 20.0 μg/L. The LOD was found to be 0.67 μg/L. The specificity towards 1,4-dioxane in the presence of five chlorinated hydrocarbons was improved by using two-dimensional GC separation with optimized DMS compensation voltage. This method paves a way for developing field-deployable sensors for real-time monitoring contaminants in groundwater.
- membrane extraction device,
- gas chromatography/differential mobility spectrometry (GC/DMS),
- 1,4-dioxane,
- chlorinated hydrocarbons,
- water
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