Citation: KOU Lijuan, LIANG Rongning. Determination of tetrabromobisphenol A and bisphenol A in environmental water using carboxylated multiwalled carbon nanotubes as sorbent for solid-phase extraction combined with liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(8): 817-821. doi: 10.3724/SP.J.1123.2014.03045 shu

Determination of tetrabromobisphenol A and bisphenol A in environmental water using carboxylated multiwalled carbon nanotubes as sorbent for solid-phase extraction combined with liquid chromatography-tandem mass spectrometry

KOU Lijuan ^1,2 ,
LIANG Rongning ^1,,

1.
1. Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Provincial Key Laboratory of Coastal Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China;

Corresponding author: LIANG Rongning,
Received Date: 27 March 2014
Available Online: 8 May 2014
Fund Project: 中国科学院人才专项项目(2060299). (2060299)

A method for the determination of tetrabromobisphenol A and bisphenol A in environmental water using carboxyl-functionalized multiwalled carbon nanotubes as solid-phase extraction sorbent and liquid chromatography-tandem mass spectrometry was established. Comparison of three nanomaterials including multiwalled carbon nanotubes, C60 and carboxyl-functionalized multiwalled carbon nanotubes used as solid-phase extraction sorbents was made. After preconcentration by solid-phase extraction, tetrabromobisphenol A and bisphenol A were separated on a Thermo Scientific Hypersil C18 column (150 mm×4.6 mm, 3 μm) and then detected by tandem mass spectrometry in negative electrospray ionization (ESI) mode. The results showed a good linear response in the concentration range of 0.02-1.0 mg/L for tetrabromobisphenol A and bisphenol A, and the limits of detection (S/N=3) were 0.04 μg/L and 0.2 μg/L for tetrabromobisphenol A and bisphenol A, respectively. The application of the proposed approach has been carried out for the determination of tetrabromobisphenol A and bisphenol A in spiked lake water and sea water samples. The recoveries varied from 82% to 99% with the relative standard deviations below 5.0%. The proposed method can be used for the determination of tetrabromobisphenol A and bisphenol A at trace level in complex environmental samples.
- solid-phase extraction (SPE),
- carboxyl-functionalized multiwalled carbon nanotubes,
- tetrabromobisphenol A,
- bisphenol A,
- environmental water
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