Citation: DING Yiran, HUANG Yun, ZHAO Tingting, CAI Qian, LUO Yu, HUANG Bin, ZHANG Yuxia, PAN Xuejun. Determination of five representative ultraviolet filters in water by gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(6): 629-634. doi: 10.3724/SP.J.1123.2014.01035 shu

Determination of five representative ultraviolet filters in water by gas chromatography-mass spectrometry

DING Yiran ¹ ,
HUANG Yun ² ,
ZHAO Tingting ¹ ,
CAI Qian ¹ ,
LUO Yu ¹ ,
HUANG Bin ¹ ,
ZHANG Yuxia ² ,
PAN Xuejun ^1,,

1.
1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China;

Corresponding author: PAN Xuejun,
Received Date: 20 January 2014
Available Online: 12 March 2014
Fund Project: 国家自然科学基金项目(21267012) (21267012)高等学校博士学科点专项科研基金项目(20125314110003) (20125314110003)云南省应用基础研究计划项目(2012FB124). (2012FB124)

A method for the determination of five representative organic UV filters: ethylhexyl methoxycinnamate (EHMC), benzophenone-3 (BP-3), 4-methylbenzylidene camphor (4-MBC), octocrylene (OC), homosalate (HMS) in water was investigated. The method was based on derivatization, solid phase extraction (SPE), followed by determination with gas chromatography-mass spectrometry (GC-MS). The variables involved in the derivatization of BP-3 and HMS were optimized, and SPE conditions were studied. For derivatization, 100 μL N,O-bis(trimethylsilyl) trifluoroacetamide (BSTFA) was used as derivatization reagent and reacted with BP-3 and HMS at 100 ℃ for 100 min. For SPE, the pH value of water sample was adjusted to 3-5. The Oasis HLB cartridges were employed and the solution of ethyl acetate and dichloromethane (1:1, v/v) was used as the eluting solvent, and good recoveries of the target compounds were obtained. The limits of detection (LODs) and the limits of quantification (LOQs) for the five target compounds in water samples were 0.5-1.2 ng/L and 1.4-4.0 ng/L, respectively. The recoveries of spiked water samples were 87.85%-102.34% with good repeatability and reproducibility (RSD<5%, n=3) for all the target compounds. Finally, the validated method was applied to analysis the representative UV filters in water samples collected from a wastewater treatment plant in Kunming city of Yunnan province.
- derivatization,
- solid phase extraction (SPE),
- gas chromatography-mass spectrometry (GC-MS),
- organic ultraviolet filters,
- water sample
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