Citation: YANG Yekun, MIAO Enming, GENG Yongqin, Wei Yuling, XU Jicang, LI Xuemei, DING Zhongtao, ZHOU Jun. Pyrolysis of the Lysimachia foenum-graecum Hance extract by online pyrolysis-gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(5): 547-552. doi: 10.3724/SP.J.1123.2013.11049 shu

Pyrolysis of the Lysimachia foenum-graecum Hance extract by online pyrolysis-gas chromatography-mass spectrometry

YANG Yekun ^1,2 ,
MIAO Enming ² ,
GENG Yongqin ² ,
Wei Yuling ² ,
XU Jicang ² ,
LI Xuemei ^2,, ,
DING Zhongtao ¹ ,
ZHOU Jun ¹

1.
1. School of Chemical Science and Technology, Yunnan University, Kunming 650091, China;

Corresponding author: LI Xuemei,
Received Date: 26 November 2013
Available Online: 27 March 2014
Fund Project: 云南省技术创新人才培养资助项目(2010CI059) (2010CI059)云南中烟工业有限责任公司资助项目(2010JC05). (2010JC05)

In order to study the pyrolytic properties of Lysimachia foenum-graecum Hance extract, it was pyrolysed and detected by online pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS). The pyrolytic experimental conditions were designed to simulate the real combustion conditions inside a burning cigarette. The sample was heated at 30 ℃/s from 300 to 900 ℃ (held for 5 s) under the flow of 9% oxygen in nitrogen. The pyrolytic components and volatile components were compared. The results showed that 64 pyrolytic components were detected, with 88.27% of the total peak area, including linoleic acid ethyl ester (10.33%), hexadecanoic acid, ethyl ester (9.12%), 9,12,15-octadecatrienoic acid, (Z,Z,Z)-(8.03%), 2-furancarboxaldehyde, 5-(hydroxymethyl)-(6.02%), neophytadiene (5.12%), heptadecanoic acid, ethyl ester(4.50%), acetic acid, phenyl ester(3.51%), 5-methoxy-2,2-di-methylindan-1-one (2.73%). The number of pyrolytic components was more than that of the volatile components, and 20 components were identified in both pyrolytic components and volatile components, including higher fatty acids and their esters, neophytadiene, 2-furancarboxaldehyde, 5-(hydroxymethyl)-, and 2(5H)-furanone, 3-hydroxy-4,5-dimethyl-. The on-line pyrolysis was similar to the real cigarette combustion conditions. The method is a simple, rapid and good qualitative method for the pyrolysis.
- gas chromatography-mass spectrometry (GC-MS),
- cold trapping,
- volatile components,
- Lysimachia foenum-graecum hance,
- pyrolysis
1. [1]
  [1] Editorial Board of Flora of China, Chinese Academic of Sciences. Flora of China: Volume 59(1). Beijing: Science Press (中国科学院中国植物志编辑委员会. 中国植物志: 59(1)卷. 北京: 科学出版社), 1999: 42
2. [2]
  [2] Shu N, Shen H. Flavour Fragr J, 2009, 24: 1
3. [3]
  [3] Li X R, Xin B, Wang G L, et al. J Asian Nat Prod Res, 2010, 12(3): 204
4. [4]
  [4] Wen Y X, Li D P, Mo B B. Guangxi Sciences (文永新, 李典鹏, 莫彬彬. 广西科学), 2002, 9 (3): 174
5. [5]
  [5] Miao E M, Li X M, Geng Y Q, et al. Journal of Yunnan University: Natural Sciences Edition (缪恩铭, 李雪梅, 耿永勤, 等. 云南大学学报:自然科学版), 2011, 33 (6): 690
6. [6]
  [6] Pan C, Yang Y K, Chen J H, et al. Chinese Journal of Spectroscopy Laboratory (潘聪, 杨叶昆, 陈建华, 等. 光谱实验室), 2012, 29(2): 1227
7. [7]
  [7] Sun W F, Zhou Z L, Yin C Y, et al. Fine Chemicals (孙伟峰, 周志磊, 殷春燕, 等. 精细化工), 2013, 30(1): 45
8. [8]
  [8] Liu S, Yang J, Hu J, et al. Tobacco Science & Technology (刘珊, 杨军, 胡军, 等. 烟草科技), 2013(5): 27
9. [9]
  [9] Wang, B H, Wu J, Guo C S, et al. Journal of Zhengzhou University of Light Industry: Natural Science Edition (王保会, 吴键, 郭春生, 等. 郑州轻工业学院学报:自然科学版), 2013, 28(2): 69
10. [10]
  [10] Yang W Z, Xie G, Wang B X, et al. Chinese Journal of Chromatography (杨伟祖, 谢刚, 王保兴, 等. 色谱), 2006, 24(6): 606
11. [11]
  [11] Wu Y Q, Yang L, Liu F, et al. Chinese Journal of Chromatography (吴亿勤, 杨柳, 刘芳, 等. 色谱), 2007, 25(3): 408
12. [12]
  [12] Geng Y Q, Yang Y K, Miao E M, et al. Physical Testing and Chemical Analysis Part B: Chemical Analysis (耿永勤, 杨叶昆, 缪恩铭, 等. 理化检验: 化学分册), 2013, 49(2): 234
13. [13]
  [13] Stotesbury S, Digard H, Willoughby L, et al. Beitr Tabakforsch Int, 1999, 18(4): 147
14. [14]
  [14] Baker R R, Bishop L J. J Anal Appl Pyrolysis, 2005, 74: 145
15. [15]
  [15] Xu J C, Li X M, Geng Y Q, et al (徐济仓, 李雪梅, 耿永勤, 等), CN101871922A. [2010-06-18]
16. [16]
  [16] Yang Y K, Geng Y Q, Miao E M, et al. Tobacco Science & Technology (杨叶昆, 耿永勤, 缪恩铭, 等. 烟草科技), 2012(8): 40
17. [17]
  [17] Zhang Y J, Jin W B. Tobacco Flavor and Perfume. Hefei: University of Science and Technology of China Press (张悠金, 金闻博. 烟用香料香精. 合肥: 中国科学技术大学出版社), 1996: 175
18. [18]
  [18] Sun B G. The Edible Flavouring Technique. Beijing: Chemical Industry Press (孙宝国. 食用调香术. 北京: 化学工业出版社), 2003: 140
19. [19]
  [19] Yang Y, Cao Q E, Xu J C, et al. Chinese Journal of Spectroscopy Laboratory (杨燕, 曹秋娥, 徐济仓, 等. 光谱实验室), 2006, 23(6): 1288
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