Citation: FENG Yuechao, JIA Li, HE Yahui, WANG Jianfeng, LIU Yan, FAN Xiaojing. Simultaneous determination of 24 industrial dyes in grain and meat products by ultra performance liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(10): 1021-1027. doi: 10.3724/SP.J.1123.2013.03019 shu

Simultaneous determination of 24 industrial dyes in grain and meat products by ultra performance liquid chromatography-tandem mass spectrometry

1.
Beijing Centre for Physical and Chemical Analysis, Beijing Engineering Research Center of Food Safety Analysis, Beijing 100089, China

Corresponding author: JIA Li,
Received Date: 7 March 2013
Available Online: 26 April 2013
Fund Project: 北京市科技专项项目(Z111106055311093). (Z111106055311093)

An ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) analytical method was established for the simultaneous determination of 24 forbidden industrial dyes in grain and meat products. The sample was extracted with methanol and acetonitrile, and cleaned-up by a WAX solid phase extraction column. The solution was separated on an ACQUITY UPLC BEH C18 column eluted with a mixture of 10 mmol/L ammonium acetate-0.2%formic acid aqueous solution and methanol-acetonitrile (7:3, v/v) as the mobile phases, and then analyzed in multiple reaction monitoring (MRM) mode. The correlation coefficients were above 0.99, the average recoveries were 61%-116%, and the relative standard deviations (RSD, n=6) were lower than 13%. The quantification limits were 0.1-4.0 μg/kg. This method is simple, effective, sensitive, and suitable for the determination and confirmation of the 24 forbidden industrial dyes in grain and meat products.
- ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS),
- solid phase extraction (SPE),
- industrial dyes,
- grain,
- meat products
1. [1]
  [1] He F Y, Wan Y P, Li J, et al. Journal of Animal Science and Veterinary Medicine (何方洋, 万宇平, 李静, 等. 畜牧兽医杂志), 2011, 30(3): 4
2. [2]
  [2] Du J Z, Xie W W, Cai Q L, et al. Food Science (杜建中, 谢薇薇, 蔡泉林, 等. 食品科学), 2012, 33(4): 173
3. [3]
  [3] Zhang W D. Chinese Journal of Food Hygiene (张文德. 中国食品卫生杂志), 2006, 18(4): 317
4. [4]
  [4] Zhang Y. Chinese Journal of Health Laboratory Technology (张杨. 中国卫生检验杂志), 2006, 16(5): 559
5. [5]
  [5] Wu Y L, Li C, Liu Y J, et al. Chinese Journal of Analytical Chemistry (吴银良, 李存, 刘勇军, 等. 分析化学), 2008, 36(6): 843
6. [6]
  [6] Fan W R, Wu Q, Lao Y, et al. Chinese Journal of Analytical Chemistry (范文锐, 吴青, 劳杨, 等. 分析化学), 2012, 40(2): 292
7. [7]
  [7] Liu M, Li X L, Bie W, et al. Chinese Journal of Chromatography (刘敏, 李小林, 别玮, 等. 色谱), 2011, 29(2): 162
8. [8]
  [8] Liu J, Gong Z B. Chinese Journal of Chromatography (刘珺, 弓振斌. 色谱), 2012, 30(6): 624
9. [9]
  [9] Zacharis C K, Kika F S, Tzanavaras P D, et al. Talanta, 2011, 84(2): 480
10. [10]
  [10] Zhang S B, Han C, Liu J D, et al. Journal of Chinese Institute of Food Science and Technology (张胜邦, 韩超, 刘继东, 等. 中国食品学报), 2009, 9(2): 187
11. [11]
  [11] Zhao S, Zhang J, Yang Y, et al. Chinese Journal of Chromatography (赵珊, 张晶, 杨奕, 等. 色谱), 2010, 28(4): 356
12. [12]
  [12] Feng F, Yang S, Ling Y, et al. Chinese Journal of Analytical Chemistry (冯峰, 杨烁, 凌云, 等. 分析化学), 2011, 39(11): 1732
13. [13]
  [13] Yi X H, Deng X J, Yang H Q, et al. Chinese Journal of Chromatography (伊雄海, 邓晓军, 杨惠琴, 等. 色谱), 2011, 29(11): 1062
14. [14]
  [14] Cao P, Qiao X G, Lou X S, et al. Chinese Journal of Analytical Chemistry (曹鹏, 乔旭光, 娄喜山, 等. 分析化学), 2011, 39(11): 1670
15. [15]
  [15] Hu X, Xiao G, Pan W, et al. Chinese Journal of Chromatography (胡侠, 肖光, 潘玮, 等. 色谱), 2010, 28(6): 590
16. [16]
  [16] Ning X J, Ge Y, Wang D L, et al. Food Science and Technology (宁啸骏, 葛宇, 王丁林, 等. 食品科技), 2007, 32(11): 189
17. [17]
  [17] Chen H W, Zhang X, Luo M B. Chinese Journal of Analytical Chemistry (陈焕文, 张燮, 罗明标. 分析化学), 2006, 34(4): 464
18. [18]
  [18] Li S J, Tu H Y, Sun L, et al. Chinese Journal of Chromatography (李赛君, 屠海云, 孙岚, 等. 色谱), 2011, 29(1): 79
19. [19]
  [19] Ning X J, Wang D L, Yu C H, et al. Journal of Chinese Mass Spectrometry Society (宁啸骏, 王丁林, 虞成华, 等. 质谱学报), 2009, 30(1): 41
20. [20]
  [20] Ma M, Luo X, Chen B, et al. J Chromatogr A, 2006, 1103: 170
21. [21]
  [21] Calbiani F, Careri M, Elviri L. J Chromatogr A, 2004, 1042: 123
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沈阳化工大学材料科学与工程学院沈阳 110142