Citation: QIU Xiuzhen, GUO Huishi, CHEN Buqing. Determination of three phenolic compounds in water samples by solid phase extraction with microemulsion liquid chromatography[J]. Chinese Journal of Chromatography, ;2013, 31(8): 809-812. doi: 10.3724/SP.J.1123.2013.01029 shu

Determination of three phenolic compounds in water samples by solid phase extraction with microemulsion liquid chromatography

1.
College of Chemistry and Environmental Engineering, Shaoguan University, Shaoguan 512005, China

Corresponding author: GUO Huishi,
Received Date: 14 January 2013
Available Online: 22 March 2013
Fund Project: 教育部留学回国人员科研启动基金项目(第39批) (第39批)广东省自然科学基金项目(9151200501000008) (9151200501000008)

A method for the determination of phenol, bisphenol A (BPA), 2,4-dichlorophenol in water samples based on solid-phase extraction with microemulsion liquid chromatography(MELC) was established. The water sample was acidified, and then cleaned-up by a C18 solid-phase extraction cartridge. The separation was carried out on an Inertsil C18 (150 mm×4.6 mm, 5 μm) with a gradient elution using a microemulsion (consisting of 3.0% sodium dodecyl sulfate (SDS), 6.0% butyl alcohol, 0.8% n-heptane, 90.2% (water+0.5% acetic acid)) and acetonitrile as mobile phases at a flow rate of 1.0 mL/min and a detection wavelength of 280 nm. The detection limits (S/N=3) of phenol, BPA, 2,4-dichlorophenol were 0.74, 8.0, 8.0 μg/L, respectively. Good linearities were achieved for the target compounds over the range of 0.1-10 mg/L. The spiked recoveries of three phenolic compounds in blank water samples were 82.7%, 87.8%, 82.6% for phenol, BPA, 2,4-dichlorophenol respectively. The recoveries of target compounds in real water samples ranged from 85.7% to 113.2%. The developed method is simple, selective, sensitive and applicable for the analysis of environmental water samples.
- solid-phase extraction (SPE),
- microemulsion liquid chromatography (MELC),
- phenol,
- bisphenol A,
- 2,4-dichlorophenol
1. [1]
  [1] Zhou Y L. Journal of Environmental Monitoring Management and Technology (周艳玲. 环境监测管理与技术), 2011, 23(Suppl): 70
2. [2]
  [2] Liu J F, Sun J, He Z G. Chinese Journal of Analytical Chemistry (刘建芳, 孙进, 何仲贵. 分析化学), 2007, 35(10): 1529
3. [3]
  [3] Zhang T, Cui Y. Chinese Journal of Chromatography (张婷, 崔颖. 色谱), 2011, 29(8): 768
4. [4]
  [4] Li N, Huang G L, Li Y L, et al. Chinese Journal of Analytical Chemistry (李宁, 黄光亮, 李玉兰, 等. 分析化学), 2009, 37(12): 1791
5. [5]
  [5] Li N, Hou X Z, Wang J X, et al. Journal of Instrumental Analysis (李宁, 侯璇珠, 王锦旋, 等. 分析测试学报), 2010, 29(2): 115
6. [6]
  [6] Marsh A, Clark B J, Altria K D. Chromatographia, 2005, 61: 539
7. [7]
  [7] Yang J R, Huang L N, Huang G L, et al. Chinese Journal of Chromatography (杨建锐, 黄丽娜, 黄光亮, 等. 色谱), 2011, 29(10): 995
8. [8]
  [8] McEvoy E, Donegan S, Power J, et al. Chromatographia, 2008, 68: 49
9. [9]
  [9] He S, Zhang Z Y, Zhang S Y. Journal of Instrumental Analysis (贺帅, 张忠义, 张守尧. 分析测试学报), 2008, 27(6): 654
10. [10]
  [10] Chen L J, Zhang Z Y, Zhang S Y. Journal of Instrumental Analysis (陈莉婧, 张忠义, 张守尧. 分析测试学报), 2009, 28(10): 1217
11. [11]
  [11] Ren J B, Dai M, Li N. Journal of Instrumental Analysis (任晶波, 戴敏, 李宁. 分析测试学报), 2011, 30(5): 562
12. [12]
  [12] Altria K D, Marsh A, Clark B J. Chromatographia, 2006, 63: 309
1. [1]
  Jiaxi Xu , Yuan Ma . Stable Conformation of Several Common Aromatic Compounds. University Chemistry, 2025, 40(12): 183-186. doi: 10.12461/PKU.DXHX202508007
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
5. [5]
  Shan Zhao , Xu Liu , Haotian Guo , Zonglin Liu , Pengfei Wang , Jie Shu , Tingfeng Yi . Synergistic design of high-entropy P2/O3 biphasic cathodes for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(1): 100129-0. doi: 10.1016/j.actphy.2025.100129
6. [6]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
7. [7]
  Bowen Liu , Jianjun Zhang , Han Li , Bei Cheng , Chuanbiao Bie . MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation. Acta Physico-Chimica Sinica, 2025, 41(10): 100121-0. doi: 10.1016/j.actphy.2025.100121
8. [8]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
9. [9]
  Xiaojun Liu , Lang Qin , Yanlei Yu . Dynamic Manipulation of Photonic Bandgaps in Cholesteric Liquid Crystal Microdroplets for Applications. Acta Physico-Chimica Sinica, 2024, 40(5): 2305018-0. doi: 10.3866/PKU.WHXB202305018
10. [10]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
11. [11]
  Tong Wang , Liangyu Hu , Shiqi Chen , Xinqiang Fu , Rui Wang , Kun Li , Shuangyan Huan . Determination of Benzenediol Isomers in Cosmetics Using High-Performance Liquid Chromatography Empowered by “Mathematical Separation”. University Chemistry, 2026, 41(1): 9-19. doi: 10.12461/PKU.DXHX202503128
12. [12]
  Xiaoyong ZHAI , Yao KOU , Pingru SU , Yu TANG . Lanthanide metal-organic framework with msw topology: Synthesis and the application in 2, 4, 6-trinitrophenol detection. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2087-2094. doi: 10.11862/CJIC.20250182
13. [13]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
14. [14]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
15. [15]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
16. [16]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
17. [17]
  Yongqing Kuang , Jie Liu , Jianjun Feng , Wen Yang , Shuanglian Cai , Ling Shi . Experimental Design for the Two-Step Synthesis of Paracetamol from 4-Hydroxyacetophenone. University Chemistry, 2024, 39(8): 331-337. doi: 10.12461/PKU.DXHX202403012
18. [18]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
19. [19]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
20. [20]
  Cuiping HE , Zhuxuan LI , Yuqing SUN , Jie LIU , Shicheng XU , Zhanchao WU . Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(492)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142