Citation: DU Ying-Qiu, YIN Yi-Dong, FAN Nai-Ying, CHEN Peng-Gang, ZHANG Xiao-Bo, JIN Hai-Tao, SHAN Hong, QU Qiu-Yao, SUN Zhi-Bo, CHEN Yue-Xin. Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(12): 1890-1896. doi: 10.3724/SP.J.1096.2012.20408 shu

Determination of Trace Nickel(Ⅱ) by Inductively Coupled Plasma Mass Spectrometry after Pre-concentration/Separation with Monoclinic Fusiform Nanometer-Size Zirconium Dioxide

1.
¹ School of Chemical Engineering & Materials, Heilongjiang University, Haerbin 150080, China;

Corresponding author: YIN Yi-Dong,
Received Date: 18 April 2012
Available Online: 17 August 2012
Fund Project: 本文系国家自然科学基金(No.20871043)资助 (No.20871043)

Monoclinic fusiform zirconium dioxide (ZrO₂) nanoparticles were synthesized by hydrothermal method, a method for the determination of Nickel²⁺ was developed by inductively coupled plasma mass spectrometry(ICP-MS) with monoclinic fusiform nanometer-sized ZrO₂ as absorbent. The detection limit to Ni²⁺ was 0.029 μg/L and the relative standard deviation was 2.7% (n=6). Optimal adsorption and elution conditions of nanometer-sized ZrO₂ to Ni²⁺ were studied, adsorption percentage of nanometer-sized ZrO₂ to Ni²⁺ was more than 99% under pH 9.0 and 10 min, 2 mL 0.5 mol/L HCl was sufficient for elution to Ni²⁺ more than 98%. The static adsorption capacity of ZrO₂ to Ni²⁺ was 198.4 μg/g and enrichment factor reached 250. Effects of co-existing ions and regeneration properties were discussed. The method has been applied to the determination of trace Ni²⁺ in real water samples, the recoveries were 96.3%-101.4%.
- Nanometer-sized zirconium dioxide,
- Pre-concentration,
- Separation,
- Inductively coupled plasma mass spectrometry,
- Nickel
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