Citation: ZHU Sheng-Nan, ZHANG Jing, LI Qing-Wen, LI Hong-Bo, JIN He-Hua, SONG Qi-Jun. Separation of Metallic Single-walled Carbon Nanotubes and Semiconducting Single-walled Carbon Nanotubes by Agarose Gel Electrophoresis[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(12): 1839-1844. doi: 10.3724/SP.J.1096.2012.20360 shu

Separation of Metallic Single-walled Carbon Nanotubes and Semiconducting Single-walled Carbon Nanotubes by Agarose Gel Electrophoresis

1.
¹ School of Chemistry and Material Engineering, Jiangnan University, Wuxi 214000, China;

Corresponding author: SONG Qi-Jun,
Received Date: 6 April 2012
Available Online: 2 July 2012
Fund Project: 本文系国家自然科学基金(Nos.20903069,21175060)资助项目 (Nos.20903069,21175060)

The agarose gel electrophoresis(AGE) is one of the low-cost, large scale technologies for the separation of metallic single-walled carbon nanotubes(m-SWCNTs) and semiconducting single-walled carbon nanotubes(s-SWCNTs). The separated m-SWCNTs are divided into several parts and characterized by the UV-visible-near infrared absorption spectrum and the Raman spectrum respectively. The results show that the moieties with the fastest electrophoresis migration rate contain more m-SWCNTs. Furthermore, the effects of different agarose concentrations on the separating efficiencies of SWCNTs are investigated. It is found that higher concentration of agarose gel is beneficial to the enrichment of the m-SWCNTs and the separating efficiency of the m-SWCNTs could be realized by increasing the charge density on the surface of the SWCNTs.
- Single-walled carbon nanotube,
- Agarose gel electrophoresis,
- Ultraviolet-visible-near infrared absorption spectrum,
- Raman spectrum
1. [1]
  1 Wu Z C, Chen Z H, Du X, Logan J M, Sippel J, Nikolou M, Kamaras K, Reynolds J R, Tanner D B, Hebard A F, Rinzler A G. Science, 2004, 305(5688): 1273-1277
2. [2]
  2 SUN Bin-Jie, WANG Ya-Nan, SHAO Nan, HU Xin-Fang, OUYANG Jin. Chinese J. Anal. Chem., 2009, 37: D027
3. [3]
  孙斌杰, 王亚男, 邵娜, 胡昕芳, 欧阳津. 分析化学, 2009, 37: D027
4. [4]
  3 QI Yu-Bing, LIU Ying, SONG Qi-Jun. Chinese J. Anal. Chem., 2011, 39(7): 1053-1057
5. [5]
  齐玉冰, 刘瑛, 宋启军. 分析化学, 2011, 39(7): 1053-1057
6. [6]
  4 Yao Z, Kane C L, Dekker C. Phys. Rev. Lett., 2000, 84(13): 2941-2944
7. [7]
  5 Wind S J, Appenzeller J, Martel R, Derycke V, Avouris P. Appl. Phys. Lett., 2002, 80(20): 3817-3819
8. [8]
  6 Ren Z F, Huang Z P, Xu J W, Wang J H, Bush P, Siegel M P, Provencio P N. Science, 1998, 282(5391): 1105-1107
9. [9]
  7 Krupke R, Hennrich F, Lehneysen H V, Kappes M M. Science, 2003, 301(5631): 344-347
10. [10]
  8 Green A A, Hersam M C. Nano Lett., 2008, 8(5): 1417-1422
11. [11]
  9 Huang H J, Maruyama R, Noda K, Kajiura H, Kadono K. J. Phys. Chem. B, 2006, 110(14): 7316-7320
12. [12]
  10 Zheng M, Jagota A, Strano M S, Santos A P, Barone P, Chou S G, Diner B A, Dresselhaus M S, Mclean R S, Onoa G B, Samsonidze G G, Semke, E D, Usrey M, Walls D J. Science, 2003, 302(5650): 1545-1548
13. [13]
  11 Tanaka T, Urabe Y, Nishide D, Kataura H. Appl. Phys. Express, 2009, 2(12): 125002/1-125002/3
14. [14]
  12 Tanaka T, Jin H, Miyata Y, Kataura, H. Appl. Phys. Express, 2008, 1(11): 114001/1-114001/3
15. [15]
  13 Tanaka T, Jin H, Miyata Y, Fujii S, Nishide D, Kataura H. Phys. Status Solidi B, 2009, 246(11-12): 2490-2493
16. [16]
  14 Tanaka T, Jin H, Miyata Y, Fujii S, Suga H, Naitoh Y, Minari T, Miyadera T, Tsukagoshi K, Kataura H. Nano Lett., 2009, 9(4): 1497-1500
17. [17]
  15 WEN Xiao-Nan, ZHANG Jing, GU Wen-Xiu, JIN He-Hua, LI Hong-Bo, LI Qing-Wen. Acta. Phys. Chim. Sin., 2010, 26(10): 2757-2762
18. [18]
  温晓南, 张静, 顾文秀, 金赫华, 李红波, 李清文. 物理化学学报, 2010, 26(10): 2757-2762
19. [19]
  16 ZHANG Jing, WEN Xiao-Nan, LI Hong-Bo, JIN He-Hua, SONG Qi-Jun, LI Qing-Wen. Chem. J. Chinese Universities, 2010, 31(11): 2190-2195
20. [20]
  张静, 温晓南, 李红波, 金赫华, 宋启军, 李清文. 高等学校化学学报, 2010, 31(11): 2190-2195
21. [21]
  17 O'Connell M J, Bachilo S M, Huffman C B, Moore V C, Strano M S, Haroz E H, Rialon K L, Boul P J, Noon W H, Kittrell C, Ma J P, Hauge R H, Weisman R B, Smalley R E. Science, 2002, 297(5581): 593-596
22. [22]
  18 Kataura H, Kumazawa Y, Maniwa Y, Umezu I, Suzuki S, Ohtsuka Y, Achiba Y. Synthetic Met., 1999, 103(1-3): 2555-2558
23. [23]
  19 Ding L, Tselev A, Wang J Y, Yuan D N, Chu H B, McNicholas T P, Li Y, Liu J. Nano Lett., 2009, 9(2): 800-805
24. [24]
  20 Miyata Y, Yanagi K, Maniwa Y, Kataura H. J. Phys. Chem. C, 2008, 112(34): 13187-13191
25. [25]
  21 Javey A, Guo J, Wang Q, Lundstrom M, Dai H J. Nature, 2003, 424(6949): 654-657
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