Citation: LIU Min-Min, WEI Wen-Tao, LU Yi-Zhong, WU Hai-Bin, CHEN Wei. Synthesis of Graphene-Supported Hollow AgPd Alloy Nanoparticles and Application in Detection of Hydrogen Peroxide[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(10): 1477-1481. doi: 10.3724/SP.J.1096.2012.20281 shu

Synthesis of Graphene-Supported Hollow AgPd Alloy Nanoparticles and Application in Detection of Hydrogen Peroxide

LIU Min-Min ^1,2 ,
WEI Wen-Tao ¹ ,
LU Yi-Zhong ^1,2 ,
WU Hai-Bin ¹ ,
CHEN Wei ^1,,

1.
¹ State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

Corresponding author: CHEN Wei,
Received Date: 19 March 2012
Available Online: 6 June 2012
Fund Project: 本文系国家自然科学基金(No.21043013) (No.21043013) 吉林省自然科学基金(No.201215090) (No.201215090)

We demonstrate a novel method to synthesize the graphene-supported AgPd alloy nanocrystals (AgPd/GO) which exhibits unique hollow structure and excellent electrocatalytic activity for H₂O₂ reduction. The hybrid nanomaterials were synthesized via a two-step method. The graphene supported Ag nanoparticles (Ag/GO) were first synthesized by using sodium citrate as both reducing and stabilizing agents. AgPd alloy nanoparticles supported on graphene (AgPd/GO) were then prepared through a galvanic displacement reaction at 100 ℃. The structure of the prepared materials was characterized with UV-visible spectroscopy and transmission electron microscopy (TEM). The electrochemical measurements showed that AgPd/GO had excellent electrocatalytic activity toward the reduction of hydrogen peroxide. Such hollow Ag/Pd alloy nanoparticles supported on graphene exhibited a low detection limit (1.4 μmol/L) and good linear ranges (0.01 mmol/L-1.4 mmol/L) for H₂O₂ detection, which render them the suitable electrochemical sensors for hydrogen peroxide detection in practical applications.
- Silver-palladium alloy,
- Nanoparticles,
- Graphene,
- Electrocatalysis,
- Hydrogen peroxide
1. [1]
  1 Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306(5696): 666-669
2. [2]
  2 Niyogi S, Bekyarova E, Itki M E, McWilliams J L, Hamon M A, Haddon R C. J. Am. Chem. Soc., 2006, 128(24): 7720-7721
3. [3]
  3 Zhang Y, Tan Y W, Stormer H L, Kim P. Nature, 2005, 438: 201-204
4. [4]
  4 Kamat P. J. Phys. Chem. Lett., 2010, 1(2): 520-527
5. [5]
  5 Shan C S, Yang H F, Song J F, Han D X, Ivaska A, Niu L. Anal. Chem., 2009, 81(6): 2378-2382
6. [6]
  6 Pasricha R, Gupta S, Srivastava A K. Small, 2009, 5(20): 2253-2259
7. [7]
  7 Cui K, Song Y H, Yao Y, Huang Z Z, Wang L. Electrochem. Commun., 2008, 10(4): 663-667
8. [8]
  8 Xu C, Wang X. Small, 2009, 5(19): 2212-2217
9. [9]
  9 Zhang Z, Chen H, Xing C, Guo M, Xu F, Wang X, Gruber H, Zhang B, Tang J L. Nano Res., 2011, 4(6): 599-611
10. [10]
  10 Lim S H, Wei J, Lin J, Li Q, KuaYou J. Biosens. Bioelectron., 2005, 20(11): 2341-2346
11. [11]
  11 DONG She-Ying, GU Guang-Zhe, YU Zhu-Qing, ZHOU Yuan-Zhen, TANG Hong-Sheng, ZHENG Jian-Bin. Chinese J. Anal. Chem., 2011, 39(9): 1358-1362
12. [12]
  董社英, 谷广哲, 于竹青, 周元臻, 汤宏胜, 郑建斌. 分析化学,2011,39(9): 1358-1362
13. [13]
  12 Hummers W. S, Offeman R E. J. Am. Chem. Soc., 1958, 80(6): 1339
14. [14]
  13 Cote L J, Kim F, Huang J. J. Am. Chem. Soc., 2009, 131(3): 1043-1049
15. [15]
  14 Lee P C, Meisel D. J. Phys. Chem., 1982, 86(17): 3391-3395
16. [16]
  15 Li J, Liu C Y. Eur. J. Inorg. Chem., 2010, 2010(8): 1244-1248
17. [17]
  16 Quan H, Park S U, Park J. Electrochim. Acta, 2010, 55(7): 2232-2237
18. [18]
  17 Wu X L, Kuang H, Chang C L, Xing C R, Wang L B, Xu C L. Biosens. Bioelectron., 2012, 33(1): 309-312
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