Citation: ZHANG Yao-Hai, JIAO Bi-Ning, ZHOU Zhi-Qin. Analysis of Eight Photoinitiator Residues in Soft Drinks Using QuEChERS Method and Gas Chromatography-Tandem Mass Spectrometric Detection[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(10): 1536-1542. doi: 10.3724/SP.J.1096.2012.20197 shu

Analysis of Eight Photoinitiator Residues in Soft Drinks Using QuEChERS Method and Gas Chromatography-Tandem Mass Spectrometric Detection

1.
¹ Citrus Research Institute, Southwest University, Chongqing 400712, China;

Corresponding author: ZHANG Yao-Hai,
Received Date: 28 February 2012
Available Online: 14 June 2012
Fund Project: 本文系农业部现代农业(柑桔)产业技术体系建设专项(No.CARS-27) (柑桔)产业技术体系建设专项(No.CARS-27) 重庆市自然科学基金 (No.CSTC 2009BB1136) (No.CSTC 2009BB1136) 第四十七批中国博士后科学基金面上资助项目(No.20100470808) (No.20100470808) 中央高校基本科研业务费项目(No.XDJK2012C059) (No.XDJK2012C059)948计划项目(No.2012-2013)资助 (No.2012-2013)

A fast method based on the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) sample preparation method and gas chromatography-tandem mass spectrometry (GC-MS/MS) for the analysis of eight photoinitiator residues in various soft drinks including orange juice, cider, peach juice, pineapple juice and herb tea was developed. The procedure involved the quick extraction of the sample with acetonitrile, followed by adding NaCl plus anhydrous MgSO₄. Then the extract was purified by primary secondary amine (PSA) sorbent plus C₁₈ power. The ultimate solution was detected by GC-MS/MS under multiple reaction monitoring mode. The recoveries of eight photoinitiators were in the range from 60.4% to 99.1% at three spike levels of 0.01, 0.1 and 0.5 mg/kg into five soft drinks matrices, the relative standard deviations (RSDs) were between 1.2% and 15.9% and the limits of detection were between 0.2 μg/L and 0.8 μg/L. The method is simple, quick, safe, cheap and reproducible, and applicable to confirm photoinitiator residues in the real sample.
- Quick easy cheap effective rugged and safe method,
- Gas chromatography-tandem mass spectrometry,
- Photoinitiators,
- Soft drinks
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沈阳化工大学材料科学与工程学院沈阳 110142