Citation: WU Hong-Wei, CHEN Mei-Lan, SHOU Dan, ZHU Yan. Determination of Resorcinol and Phloroglucinol in Environmental Water Samples Using Ion Chromatography with Chemiluminescence Detection[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1747-1751. doi: 10.3724/SP.J.1096.2012.20138 shu

Determination of Resorcinol and Phloroglucinol in Environmental Water Samples Using Ion Chromatography with Chemiluminescence Detection

WU Hong-Wei ^1,2 ,
CHEN Mei-Lan ³ ,
SHOU Dan ^4,, ,
ZHU Yan ^2,,

1.
¹ Department of Chemistry, Xinxiang Medical University, Xinxiang 453003, China;

Corresponding author: SHOU Dan, ZHU Yan,
Received Date: 17 February 2012
Available Online: 16 June 2012
Fund Project: 本文系国家自然科学基金(No. J0830413) (No. J0830413)浙江省自然科学基金(No. Y5100280) (No. Y5100280)浙江省分析测试基金(No. 2011C 37034)资助项目 (No. 2011C 37034)

A novel method was established for the simultaneous determination of resorcinol and phloroglucinol in environmental water samples by ion chromatography with chemiluminescence detection. Using 50 mmol NaOH solution as eluent, resorcinol and phloroglucinol can be well separated with IonPac AS19 column and determined based on the chemiluminescence reaction of luminol and potassium ferricyanide in an alkaline medium.The optimal CL conditions were 6.0×10^-4 mol/L luminol, 0.1 mol/L potassium ferrocyanide and 5.5×10^-5 mol/L potassium ferricyanide. The absence of methanol and acetonitrile in mobile phase made the proposed method more sensitive. Under the optimal conditions, the detection limits (LOD) of resorcinol and phloroglucinol were 4.0 μg/L and 4.3 μg/L, respectively. The method showed good linearity within the range of 0.05-1.0 mg/L. The relative standard deviations (RSD) for 0.1 mg/L resorcinol and phloroglucinol standard solutions were 0.9% and 1.1% (n=11). The method has been applied to the determination of resorcinol and phloroglucinol in environmental water samples successfully.
- Ion chromatography,
- Chemiluminescence,
- Environmental water samples,
- Resorcinol,
- Phloroglucinol
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