Citation: ZHANG Ming, TANG Fang-Liang, FAN Xiao-Kai, XU Jian-Fen, CHEN Feng, WU Zhi-Xu. Determination of Three Amide Compounds in Environmental Water by Solid Phase Extraction Coupled with Hydrophilic Interaction Liquid Chromatography[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(10): 1555-1560. doi: 10.3724/SP.J.1096.2012.20064 shu

Determination of Three Amide Compounds in Environmental Water by Solid Phase Extraction Coupled with Hydrophilic Interaction Liquid Chromatography

1.
¹ Hangzhou Environmental Monitoring Central station, Hangzhou 310007, China;

Corresponding author: ZHANG Ming,
Received Date: 18 January 2012
Available Online: 25 April 2012
Fund Project: 本文系杭州市环境保护科技项目(No.2011003)资助 (No.2011003)

A simple hydrophilic interaction liquid chromatographic (HILIC) method for the determination of acrylamide (AA), N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMAC) in environmental water was developed. A cartridge containing graphitized carbon black was used for solid phase extraction (SPE) of the compounds in environmental water, the sample loaded was 1.0 mL, and then eluted with 1.0 mL acetonitrile, the elution was introduced into the instrument and determined by HPLC coupled with photo-diode array detector (PDA) at 200 nm. A good baseline separation of target compounds was obtained in 11 minutes under the optimum condition of determination. The calibration curves of 3 amides were linear in the concentration range of 0.05-100 mg/L with correlation coefficients of 0.9999. Overall recoveries were good (84.1%-106%), and the relative standard deviations ranged from 1.8% to 10.4% for the target compounds. The minimum detectable concentrations were 0.01 mg/L. This established method is convenient, sensitive and accurate, and was suitable for the routine detection of trace amide contaminants in environmental water.
- Hydrophilic interaction liquid chromatography,
- Solid phase extraction,
- Amide,
- Environmental water
1. [1]
  1 LIU De-Hui, New Practical Handbook of hazardous chemicals. Beijing: China Logistics Publishing House, 1995: 223
2. [2]
  刘德辉. 化学危险品最新实用手册. 北京:中国物资出版社, 1995: 223
3. [3]
  2 JIANG Chao-Qiang. Organic solvent poisoning prevention guidelines. Beijing: Chemical Industry Press, 2006: 487
4. [4]
  江朝强. 有机溶剂中毒预防指南. 北京:化学工业出版社, 2006: 487
5. [5]
  3 CAO Bing-Yan. Petroleum and Chemical Toxicology Handbook. Beijing: China Labor Press, 1992: 50-51
6. [6]
  曹炳炎. 石油化工毒物手册. 北京: 中国劳动出版社, 1992: 50-51
7. [7]
  4 World Health Organization. Environmental Health Critera 49 "Acrylamide", 1985
8. [8]
  5 YANG Ye, QIAO Shan-Lei, CHEN Jing-Heng, ZHAO Ren-Zheng, AO Shu-Qing, LU Xiao-Mei, MAO Li, SHEN Dong-Xu, LIAN Hong-Zhen. Chinese J.Anal.Chem., 2010, 38(10):1487-1491
9. [9]
  杨叶, 乔善磊, 陈景衡, 赵人琤, 敖淑清, 陆晓梅, 茅力, 沈东旭, 练鸿振. 分析化学, 2010, 38(10): 1487-1491
10. [10]
  6 Brian A, Jane B. Prog Polym Sci, 1995, 20(6): 1014-1016
11. [11]
  7 Marín J M, Pozo O J, Sancho J V, Pitarch E, López F J, Hernández F. J. Mass Spectrom, 2006, 41(8): 1041-1048
12. [12]
  8 Standards for Drinking Water Quality. National Standards of the People's Republic ofChina, GB 5749-2006
13. [13]
  生活饮用水卫生标准. 中华人民共和国国家标准. GB 5749-2006
14. [14]
  9 Environmental Quality Standards for Surface Water. National Standards of the People's Republic of China. GB 3838-2002
15. [15]
  地表水环境质量标准. 中华人民共和国国家标准. GB 3838-2002 10 Emission Standard of Pollutants for Synthetic Leather and Artificial Leather Industry. National Standards of the People's Republic of China. GB 21902-2008
16. [16]
  合成革与人造革工业污染物排放标准. 中华人民共和国国家标准. GB 21902-2008 11 Methods for Determination of Amides in the Air of Workplace. National Standards of the People's Republic ofChina. GBZ/T 160.62-2004
17. [17]
  工作场所空气有毒物质测定—酰胺类化合物. 中华人民共和国国家标准. GBZ/T 160.62-2004 12 Kawata K, Ibaraki T, Tanabe A, Yagoh H, Shinoda A, Suzuki H, Yasuhara A. J. Chromatogr. A, 2001, 911(1): 75-83 13 YANG Hua-Mei. Modern Preventive Medicine, 2011, 38(6): 1099-1100
18. [18]
  杨华梅. 现代预防医学, 2011, 38(6): 1099-1100 14 ZHANG Bo, QI Yue, GAO He-Nan, BAO Jian-Min. Chinese Journal of Chromatography, 2010, 28(12): 1196-1199
19. [19]
  张勃, 祁悦, 高赫男, 包建民. 色谱, 2010, 28(12): 1196-1199 15 XIE Shan-Ling, ZHU Rui-Zhi, NI Chao-Min, XIANG Neng-Jun, MOU Ding-Rong, WANG Kai. Journal of Instrumental Analysis, 2009, 28(10): 1225-1228
20. [20]
  谢山岭, 朱瑞芝, 倪朝敏, 向能军, 牟定荣, 王凯. 分析测试学报, 2009, 28(10): 1225-1228 16 GAN Hong-Yu, ZHANG Tian-Yu. Chinese Journal of Chromatography, 2011, 29(2): 184-186
21. [21]
  甘宏宇, 张天玉.色谱, 2011, 29(02): 184-186 17 van Nuijs A L N, Tarcomnicu I, Covaci A. J. Chromatogr. A, 2011, 1218(35): 5964-5974 18 Wang G P, He W. Hydrophilic Interaction Liquid Chromatography (HILIC) and Advanced Applications, CRC Press, 2011
1. [1]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
5. [5]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
7. [7]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
8. [8]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
9. [9]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
10. [10]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
11. [11]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
12. [12]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
13. [13]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
14. [14]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
15. [15]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
16. [16]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
17. [17]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035
18. [18]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
19. [19]
  Nana Wang , Gaosheng Zhang , Huosheng Li , Tangfu Xiao . Discussion on the Teaching Reform of Environmental Functional Materials within the Context of “Double First-Class” Initiative: Emphasizing the Integration of Industry, Academia, Research, and Application. University Chemistry, 2024, 39(6): 137-144. doi: 10.3866/PKU.DXHX202312010
20. [20]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(283)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142