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Citation: ZHANG Weidong, LIAO Gongtai, YU Lei, XIE Zhengfeng. Henry Reaction Catalyzed by Mesoporous Molecular Sieve MCM-41 Supported Triazole-based Schiff Base and Cobalt Acetate[J]. Chinese Journal of Applied Chemistry, ;2014, 31(10): 1195-1202. doi: 10.3724/SP.J.1095.2014.30647 shu

Henry Reaction Catalyzed by Mesoporous Molecular Sieve MCM-41 Supported Triazole-based Schiff Base and Cobalt Acetate

1.
Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: XIE Zhengfeng,
Received Date: 20 December 2013
Available Online: 6 March 2014
Fund Project: 国家自然科学基金资助项目(21262034,20962018) (21262034,20962018)

The catalytic properties of 2-phenyl-2H-1,2,3-triazole-4-carbaldehyde functionalized mesoporous molecular sieve MCM-41 materials and cobalt acetate in the nitroaldol(Henry) reaction are reported. The catalyst was characterized by methods of Fourier transform infrared spectroscopy(FT-IR) and X-ray diffraction(XRD). The reaction conditions such as metal salts, different solvents were investigated at room temperature. And the catalyst can be separated by simple filtration and reused for several times without much loss in performance with the yield up to 80.5%.
- Schiff base,
- MCM-41,
- catalysis,
- Henry reaction
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