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Citation: ZHANG Ping, LIU Jie, HUANG Jianyan, YANG Jiaxiang. Synthesis and Properties of 3-Amino-9-butyl-6-(2-(pyridin-4-yl) vinyl)-carbazole[J]. Chinese Journal of Applied Chemistry, ;2014, 31(10): 1171-1176. doi: 10.3724/SP.J.1095.2014.30630 shu

Synthesis and Properties of 3-Amino-9-butyl-6-(2-(pyridin-4-yl) vinyl)-carbazole

1.
a College of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China;
2.
b Department of Chemistry, Anhui Science and Technolgy University, Fengyang 233100, China

Corresponding author: YANG Jiaxiang,
Received Date: 11 December 2013
Available Online: 2 April 2014
Fund Project: 国家自然科学基金(61107014) (61107014)安徽省自然科学基金(1208085MB21) (1208085MB21)安徽省教育厅自然科学基金(KJ2010B299)资助项目 (KJ2010B299)

A novel donor-π-acceptor(D-π-A) type carbazole derivative(L) was designed and synthesized through alkylation, nitration, iodination, Heck cross-coupling reaction and hydrazine hydrate reduction reaction of carbazole. Compound L was characterized by FT-IR, ¹H NMR, ¹³C NMR and MS. The optical, electrochemical properties and electronic cloud distribution of compound L were preliminarily studied by means of UV-Vis absorption spectra, fluorescent emission spectra, cyclic voltammogram and theoretical calculation. The results revealed that UV-Vis absorption and fluorescence spectra of compound L red-shifted with the increasing solvent polarity.
- carbazole derivative,
- structural characterization,
- optical properties
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