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Citation: LIN Meijuan, AN Qi, HU Zhen, ZENG Huijuan, LING Qidan. Polyethylene,Polypropylene or Polystyrene Photoluminescence Composites Doped with Fatty Acid Europium Complexes[J]. Chinese Journal of Applied Chemistry, ;2014, 31(10): 1164-1170. doi: 10.3724/SP.J.1095.2014.30605 shu

Polyethylene,Polypropylene or Polystyrene Photoluminescence Composites Doped with Fatty Acid Europium Complexes

1.
Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LING Qidan,
Received Date: 29 November 2013
Available Online: 18 February 2014
Fund Project: 福建省自然科学基金(2012J01031) (2012J01031)福建省科技厅(JK2012011) (JK2012011)国家自然科学基金(61250016)资助项目 (61250016)

Fatty acid europium complexes were synthesized with hexanoic acid, octanoic acid, lauric acid or stearic acid as the ligands. The polyethylene(PE), polypropylene(PP) or polystyrene(PS) photoluminescence composites doped with europium complexes were prepared by the Haake torque rheometer. The influences of ligands, europium complexes and polymer matrixes on the appearance, transparency and luminescence properties of the composites were investigated. These fatty acid europium complexes and their composites emit strong characteristic luminescence of europium ions ⁵D₀→⁷F₁ and ⁵D₀→⁷F₂ respectively, at 593, 617 nm under ultraviolet light excitation. The luminescence of europium complexes and their composites are less affected by the chain length of the fatty acid. The PP or PE composites emit only characteristic red fluorescence of the Eu³⁺ ions under ultraviolet light, while a rosy fluorescence emission of the PS composites is demonstrated to arise from a combination of strong red light-emitting of the Eu³⁺ ions and weak blue-violet light-emitting of the PS matrix.
- fatty acids,
- europium complexes,
- general resin,
- doping,
- composite,
- photoluminescence
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