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Citation: ZENG Yanfei, ZHOU Yuanlin. Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide[J]. Chinese Journal of Applied Chemistry, ;2014, 31(9): 1019-1023. doi: 10.3724/SP.J.1095.2014.30599 shu

Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide

ZENG Yanfei ,
ZHOU Yuanlin ^,

1.
State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials;School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China

Corresponding author: ZHOU Yuanlin,
Received Date: 27 November 2013
Available Online: 17 April 2014
Fund Project: 国家自然科学基金委员会-中国工程物理研究院联合基金(11176026)资助项目 (11176026)

Sodium n-butylxanthate obtained from n-butyl alcohol, sodium hydroxide and carbon disulfide in water was converted to symmetrical dibutyl xanthate disulfide by reacting with disulfur dichloride(S₂Cl₂) at room temperature. The effects of reaction conditions on the yields of the sodium n-butylxanthate and dibutyl xanthate disulfide were investigated respectively. Characterizations of dibutyl xanthate disulfide were done using Fourier transform infrared(FT-IR) spectroscopy, ¹H nuclear magnetic resonance(¹H NMR) spectroscopy, mass spectroscopy(MS) and elemental analysis techniques. In optimized reaction conditions, the molar ratio of sodium n-butylxanthate to S₂Cl₂ is 1:1.1 in THF solvent. The reaction completes within 2 min at room temperature to give up to 83.2% yield.
- sodium n-butyxanthate,
- dibutyl xanthate disulfide,
- accelerant,
- synthesis,
- structure characterization
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