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Citation: MAO Rongfang, XU Liming, GAO Xi, CHENG Guangbin, YANG Hongwei. Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate[J]. Chinese Journal of Applied Chemistry, ;2014, 31(9): 1076-1082. doi: 10.3724/SP.J.1095.2014.30592 shu

Dihydroxylation of Styrene Catalyzed by Molybdenyl Acetylacetonate

1.
School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China

Corresponding author: YANG Hongwei,
Received Date: 25 November 2013
Available Online: 17 January 2014
Fund Project: 江苏省自然科学基金(BK2011696)项目资助 (BK2011696)

The catalyst molybdenyl acetylacetonate(MoO₂(acac)₂) was prepared by reaction of ammonium molybdate and acetylacetone. The effects of solvents, temperature, oxidants, co-catalysts and the ratio of substrate on the dihydroxylation of styrene were investigated. Under the optimized condition, conversion, chemoselectivity and isolated yield of dihydroxylation reaction are 85.2%, 70.7% and 53.3%, respectively. The possible catalytic mechanism and improving directions of catalytic reaction were also discussed.
- molybdenyl acetylacetonate,
- styrene,
- dihydroxylation,
- catalytic mechanism,
- vicinal diol
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