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Citation: YOU Geyun, CHENG Zhiquan, HAO Peng, HE Hongwu. Research Progress on Synthesis and Application of Cyclotriphosphazene-based Flame Retardants[J]. Chinese Journal of Applied Chemistry, ;2014, 31(9): 993-1009. doi: 10.3724/SP.J.1095.2014.30536 shu

Research Progress on Synthesis and Application of Cyclotriphosphazene-based Flame Retardants

1.
Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: HE Hongwu,
Received Date: 30 October 2013
Available Online: 14 January 2014
Fund Project: 国家磷资源开发利用工程技术研究中心开放基金项目(2012k011)资助 (2012k011)

In this paper, the synthesis and reaction mechanism of hexachlorocyclotriphosphazene were briefly introduced. The flame-retardant mechanism of cyclotriphosphazene-based flame retardants was also summarized. The reactive-type hydroxyl, amino, epoxy, alkenyl, and carboxyl, cyclotriphosphazene and the additive-type alkoxy and aryloxy cyclotriphosphazene flame retardants were elaborated on their synthesis and application. The thermal stability and flame retardant properties of cyclotriphosphazene-based flame retardant materials were summarized. The development trend of cyclotriphosphazene-based flame retardants was also summarized and prospected.
- organophosphate flame retardants,
- hexachlorocyclotriphosphazene,
- flame-retardant mechanism,
- reactive-type,
- additive-type
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