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Citation: HUANG Hongmei, XIAO Yi, YANG Xiya, BIAN Wenhuan, YIN Dulin, MAO Liqiu. Ionic Liquid-mediated Catalytic Oxidation of Isoeugenol to Vanillin via Oxovanadium 1,3,5-Benzenetricarboxylate[J]. Chinese Journal of Applied Chemistry, ;2014, 31(8): 952-957. doi: 10.3724/SP.J.1095.2014.30510 shu

Ionic Liquid-mediated Catalytic Oxidation of Isoeugenol to Vanillin via Oxovanadium 1,3,5-Benzenetricarboxylate

HUANG Hongmei ^a,b ,
XIAO Yi ^a,b ,
YANG Xiya ^a ,
BIAN Wenhuan ^a ,
YIN Dulin ^a,b,, ,
MAO Liqiu ^a,b

1.
a National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources;
2.
b Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China

Corresponding author: YIN Dulin,
Received Date: 14 October 2013
Available Online: 10 January 2014
Fund Project: 国家自然科学基金(20572021,20805014) (20572021,20805014)湖南省教育厅科学研究基金(11C0809,12B077,12CY004)资助项目 (11C0809,12B077,12CY004)

A series of oxovanadium 1,3,5-benzenetricarboxylate complex catalysts was prepared and characterized by FT-IR,diffuse reflectance UV-Vis(DR UV-Vis) and TG,respectively. The effects of catalyst,promoter such as ionic liquid,ionic liquid amount and reaction time on the oxidation of isoeugenol to vanillin were investigated systematically. VO(BTC)-1 with a molar ratio of VO²⁺ and BTC(1,3,5-benzenetricarboxylate) as 1:1 exhibits better catalytic performance. Complete conversion of isoeugenol and 87.c% yield of vanillin are achieved using VO(BTC)-1 as catalyst,1-dodecyl-3-methylimidazolium chloride([C₁₂mim]Cl) as additive with the molar ratio of isoeugenol,H₂O₂ and [C₁₂mim]Cl as 1:2:0.01 after 24 h reaction at 20℃ in acetone. The formation of a highly effective oxidation system from [C₁₂mim]Cl/VO(BTC)-1 and H₂O₂ is beneficial in the mild conversion of isoeugenol,as indicated by spectral characterization and the reaction results.
- oxovanadium benzenetricarboxylate,
- vanillin,
- catalytic oxidation,
- ionic liquid,
- isoeugenol
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