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Citation: ZENG Wei, CHEN Fuxue. Recent Advances in Radical Trifluoromethylation Reactions[J]. Chinese Journal of Applied Chemistry, ;2014, 31(6): 627-641. doi: 10.3724/SP.J.1095.2014.30378 shu

Recent Advances in Radical Trifluoromethylation Reactions

ZENG Wei ,
CHEN Fuxue ^,

1.
School of Chemical Engineering & the Environment, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: CHEN Fuxue,
Received Date: 25 July 2013
Available Online: 29 September 2013
Fund Project: 国家自然科学基金资助项目(21172018)资助项目 (21172018)

In recent years,research on trifluoromethylation reactions have been developed rapidly.Since the special chemical and physical properties of the trifluoromethyl group,it plays an increasingly important role in the fields of medicine,pesticides and materials.As the result,a new recognition of radical trifluoromethylation has been achieved along with the development of organofluorine chemistry.This article delivered an overview of the recent progress of radical trifluoromethylation from the perspective of various radical trifluoromethylative precursors as well as reaction mechanisms.
- free radical reactions,
- trifluoromethylation,
- photoredox catalysis,
- trifluoromethyl reagent,
- single electron transfer
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