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Citation: ZHANG Fuxing, KUANG Daizhi, FENG Yonglan, WANG Jianqiu, YU Jiangxi, JIANG Wujiu, ZHU Xiaoming. Synthesis,Structure and Antitumor Activity of Tri(o-bromobenzyl) tin Dithiotetrahydropyrrolocarbamate[J]. Chinese Journal of Applied Chemistry, ;2014, 31(3): 285-289. doi: 10.3724/SP.J.1095.2014.30212 shu

Synthesis,Structure and Antitumor Activity of Tri(o-bromobenzyl) tin Dithiotetrahydropyrrolocarbamate

1.
Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province;Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: ZHANG Fuxing,
Received Date: 27 April 2013
Available Online: 15 July 2013
Fund Project: 湖南省高校创新平台开放基金项目(12K124) (12K124)湖南省自然科学基金项目(11JJ3021) (11JJ3021)

Tri(o-bromobenzyl) tin bromide was reacted with 1-pyrrolidinecarbodithioicacid sodium salt to synthesize tri(o-bromobenzyl) tin dithiotetrahydropyrrolocarbamate.The crystal structure of tri(o-bromobenzyl) tin dithiotetrahydropyrrolocarbamate was determined by X-ray diffraction.The compound crystallizes in triclinic space group P1 with cell parameters of a=0.91354(11) nm,b=1.07313(13) nm,c=1.52677(18) nm,α=75.440(6)°,β=89.499(6)°,γ=72.515(7)°,V=1.3781(3) nm³,Z=2,D_c=1.868 g/cm³,μ(MoKα)=54.43 cm^-1,F(000)=752,R₁=0.0320,wR₂=0.0765.The tin atom of the compound has a distorted tetrahedral geometry.The stabilities,some frontier molecular orbital energies and composition characteristics of some frontier molecular orbital of the complex were also investigated.Furthermore,the anticancer activity of the complexes was tested.
- tri(o-bromobenzyl) tin dithiotetrahydropyrrolocarbamate,
- synthesis,
- structure,
- antitumor activity
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