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Citation: SU Ce, XIA Shujiao, WANG Rui. N-Heterocyclic Carbene Catalyzed Oxidative Esterification of para-Nitrobenzaldehyde[J]. Chinese Journal of Applied Chemistry, ;2014, 31(2): 165-170. doi: 10.3724/SP.J.1095.2014.30110 shu

N-Heterocyclic Carbene Catalyzed Oxidative Esterification of para-Nitrobenzaldehyde

1.
College of Petro-Chemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: SU Ce,
Received Date: 10 March 2013
Available Online: 7 May 2013
Fund Project: 兰州理工大学优秀青年教师计划项目(Q200912) (Q200912)

Using air as the ultimate oxidant,a facile method for the oxidative esterification of para-nitrobenzaldehyde has been developed.The results demonstrate that the catalyst precursors,catalyst loadings and solvents have considerably effects on both the yields and reaction rates.A variety of para-nitrobenzonates were conveniently prepared with the yields of 36%~64% under the optimal reaction conditions,where the corresponding alcohols were used as the solvents,and the 3-ethyl-4-methyl-5-hydroxyethyl thiazole bromide salt as the catalyst precursor,with 10% molar fraction catalyst loading.Modest yields of 9%~29% were obtained if only stoichiometric amount alcohol was used.
- N-heterocyclic carbenes,
- para-nitrobenzaldehyde,
- oxidative esterification,
- nitrobenzoic acid esters
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