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Citation: TUO Suxing, WU Mingjian, DAI Yunhui. Reducing Polycyclic Aromatic Hydrocarbons in Cigarette Smoke by Pyrene Molecular Imprinted Polymers[J]. Chinese Journal of Applied Chemistry, ;2014, 31(1): 89-95. doi: 10.3724/SP.J.1095.2014.30081 shu

Reducing Polycyclic Aromatic Hydrocarbons in Cigarette Smoke by Pyrene Molecular Imprinted Polymers

1.
Technical Center of China Tobacco Hunan Industrial Corporation, Changsha 410007, China

Corresponding author: TUO Suxing,
Received Date: 1 February 2013
Available Online: 24 April 2013
Fund Project: 湖南中烟工业有限责任公司基金资助项目(2009-JC-0005) (2009-JC-0005)

The molecularly imprinted terpolymer was synthesized using pyrene as the template molecules by bulk polymerization.The adsorption ability and selectivity of the polymer were investigated by selectivity experiment.Scatchard analysis was employed to study the binding characteristics of molecularly imprinted polymer(MIP).Adsorption of polycyclic aromatic hydrocarbons(PAHs) was carried out to verify the interaction of MIP by solid phase extraction.The PAHs contents in the smoke of cigarette samples added with the MIPs to the filter were analyzed by GC/MS.The results show that the PYR-MIP is superior in terms of removing more than about 28% PAHs in the tobacco smoke.And the reduction rate of benzo[a]pyrene(B[a]P),benz(a) anthracene(B[a]A) and chrysene(CHR) are 31.08%,25.69% and 27.33%,respectively,compared the commercial filter tip.
- pyrene molecular imprinted polymers,
- selectivity,
- cigarette smoke,
- polycyclic aromatic hydrocarbons
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