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Citation: YANG Xiuqin, FU Changliang. Solvent-free Thionation of Carbonyl Compounds with PP₂S₅ Under Microwave Irradiation[J]. Chinese Journal of Applied Chemistry, ;2013, 30(8): 878-882. doi: 10.3724/SP.J.1095.2013.20584 shu

Solvent-free Thionation of Carbonyl Compounds with PP₂S₅ Under Microwave Irradiation

Henan Vocation College of Chemical Technology, Zhengzhou 450042, China

Received Date: 12 December 2012
Revised Date: 7 April 2013

Seven carbonyl compounds were thionated with phosphorus pentasulfide promoted by microwave irradiation under solvent-free conditions. The thiocarbonyl compounds were synthesized in 76%~93% yields. The optimized reaction conditions:the molar ratio of substrates and PP₂S₅ is 4:1,temperature is 100℃ and time is 15~20 min. The structures of products were characterized by ¹H NMR and ¹³C NMR.
- microwave-irradiation,
- solvent-free,
- thiocarbonyl reaction,
- phosphorus pentasulfide
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Solvent-free Thionation of Carbonyl Compounds with PP₂S₅ Under Microwave Irradiation