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Citation: WANG Wenge, ZHANG Dechun. One-Pot Synthesis and Extraction Performances Toward Metal Cations of Sulfonate-bridged Calixarenes[J]. Chinese Journal of Applied Chemistry, ;2013, 30(5): 511-515. doi: 10.3724/SP.J.1095.2013.20280 shu

One-Pot Synthesis and Extraction Performances Toward Metal Cations of Sulfonate-bridged Calixarenes

WANG Wenge ,
ZHANG Dechun

Department of Materials & Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Received Date: 25 June 2012
Revised Date: 20 August 2012

Four aromatic tetrasulfonate calixarenes have been prepared in one pot and their extraction performances toward Ca²⁺, Pb²⁺ and some transition metal ions in chloroform were evaluated. The primary results revealed that the sulfonate-bridged calixarenes showed improved extraction capabilities toward several toxic cations such as Cr³⁺, Cd²⁺ and CO₂₊. The extracted percentages of Cr³⁺ by compound 2a and Cd²⁺ by compound 2b are 50.15% and 46.48%,respectively.
- calixarenes,
- macrocyclic compound,
- extraction,
- sulfonate,
- metal ion recognition
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