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Citation: WANG Weidong, SUN Guofu, SHI Zhengchun, SHIMO Tetsuro. Photosynthesis of Two Oxa Macrocyclic Compounds[J]. Chinese Journal of Applied Chemistry, ;2013, 30(4): 378-382. doi: 10.3724/SP.J.1095.2013.20250 shu

Photosynthesis of Two Oxa Macrocyclic Compounds

a. College of Chemical and Materials Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China;
b. College of Chemical and Chemical Engineering, Xuchang University, Xuchang 461000, China;
c. Testing and Evaluation Center, Shenyang Research Institute of Chemical Industry, Shenyang 110071, China;
d. Faculty of Engineering, Kagoshima University, Kagoshima 890-0065, Japan

Received Date: 6 June 2012
Revised Date: 5 September 2012

Two oxa macrocyclic compounds were synthesized via double[2+2] photocycloaddition reaction between 6,6'-dimethyl-4,4'-(trimethylenedioxy)-di-2-pyrone and ethylene glycol dimethacrylates(n=1~3) by photosensitizing effect of benzophenone in acetonitrile solution with yields of 14% and 7%,20% and 11%,31% and 14%,respectively.The structures of products were identified by FTIR,¹H NMR,MS and elemental analysis.The synthetic method has several advantages such as mild reaction conditions,simple operation and environmental friendliness.
- di-pyrone,
- ethylene glycol dimethacrylate,
- cycloaddition,
- photosynthesis
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