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Citation: ZHAO Jing, ZHANG Heng, ZHU Guoyi. Synthesis and Coordination Mechanism of a Complex Formed Between D-Mannose Oxime and Copper Cations with Mixed-valence[J]. Chinese Journal of Applied Chemistry, ;2012, 29(10): 1158-1162. doi: 10.3724/SP.J.1095.2012.00524 shu

Synthesis and Coordination Mechanism of a Complex Formed Between D-Mannose Oxime and Copper Cations with Mixed-valence

ZHAO Jing ^a,b ,
ZHANG Heng ^c ,
ZHU Guoyi ^a,,

1.
a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
3.
c Instrumental Analysis Center, Hebei Normal University, Shijiazhuang 050024, China

Corresponding author: ZHU Guoyi,
Received Date: 28 November 2011
Available Online: 23 March 2012

We synthesized a complex formed between D-mannose oxime and copper cations with mixed-valence.The title compound was characterized by means of elemental analysis,IR,thermal analysis and XPS,etc.The results indicate that the compound is a tetranuclear copper complex having two Cu(Ⅱ) and two Cu(Ⅰ) metal centers.One Cu(Ⅱ) atom is coordinated by two nitrogen atoms and two oxygen atoms from two ligands while the other Cu(Ⅱ) coordinates with one nitrogen atom and three oxygen atoms.Each Cu(Ⅰ) atom bonds to three oxygen atoms and one hydroxyl ion.The four copper atoms are linked by three deprotonated D-mannose oxime molecules to form a chain.The pH plays a decisive role in the formation of the complex.
- D-mannose oxime,
- mixed-valence,
- copper complex,
- redox
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