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Citation: Tursun Abdiryim, Ruxangul Jamal, Tunsagul Awut, Ismayil Nurulla, XU Feng, SHAO Weiwei. Solid-state Synthesis and Properties of Copolymers of Aniline and o-Methoxyaniline[J]. Chinese Journal of Applied Chemistry, ;2012, 29(10): 1117-1122. doi: 10.3724/SP.J.1095.2012.00513 shu

Solid-state Synthesis and Properties of Copolymers of Aniline and o-Methoxyaniline

1.
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: Tursun Abdiryim,
Received Date: 21 November 2011
Available Online: 13 February 2012
Fund Project: 国家自然科学基金资助项目(20964004) (20964004)石油天然气精细化工教育部和自治区重点实验室开放课题(XJDX0908-2009-03) (XJDX0908-2009-03)

Copolymers of aniline and o-methoxyaniline were synthesized by solid-state polymerization method using methanesulphonic acid as the doping acid.The resultant copolymers were characterized by FTIR,UV-Vis,TEM,X-ray diffraction,cyclic voltammetry and conductivity measurements.The results showed that the copolymers prepared under different aniline and o-methoxyaniline molar ratios displayed an emeraldine salt phase,and the doping degree of copolymers decreased with increasing content of o-methoxyaniline in monomers.The as-prepared copolymers had a high crystallinity and displayed a fibrillar morphology.The copolymer prepared under the molar ratio of 1:1,exhibited a higher electrochemical activity than the others,and its conductivity was 1.65 S/cm.
- solid-state synthesis,
- copolymer,
- aniline,
- o-methoxyaniline
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