Citation:
HU Lianyue, ZHANG Shengtao, HUANG Xiaohong, TAN Jianhong, WU Yongying. Influence of Additives on the Dendrite of Zinc Electrode in KOH Solution[J]. Chinese Journal of Applied Chemistry,
;2012, 29(3): 359-363.
doi:
10.3724/SP.J.1095.2012.00171
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The influences of 6-nitrobenzimidazole,benzimidazole and Pb2+ on zinc dendrite in KOH solution(4 mol/L) were investigated by means of current-time technique.The results showed that 6-nitrobenzimidazole,benzimidazole and Pb2+ could effectively inhibit the formation of zinc dendrites,and enhance the charging capacity of zinc electrode.It showed a high charging efficiency and effective inhibition to the growth of zinc dendrites when the charging was performed at a cathodic overpotential η=-200 mV in 0.05 g/L Pb2+ alkaline solution with the addition of 6-nitrobenzimidazole or benzimidazole.
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Keywords:
- zinc dendrite,
- Pb2+,
- nitrobenzimidazole,
- benzimidazole,
- overpotential
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