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Citation: PAN Yueli, WANG Xin, ZHAO Zuzhi, WEI Wenmei. Synthesis, Crystal Structure and Optical Properties of 4-[(trans-(2-Pyridyl))styryl]-N, N-dibutylbenzenamine[J]. Chinese Journal of Applied Chemistry, ;2012, 29(2): 155-160. doi: 10.3724/SP.J.1095.2012.00133 shu

Synthesis, Crystal Structure and Optical Properties of 4-[(trans-(2-Pyridyl))styryl]-N, N-dibutylbenzenamine

1.
Department of Chemistry, College of Basic Medicine, Anhui Medical University, Hefei 230032, China

Corresponding author: PAN Yueli,
Received Date: 10 March 2011
Available Online: 6 May 2011
Fund Project: 安徽省高等学校省级自然科学研究重点项目(KJ2010A190,KJ2011Z169) (KJ2010A190,KJ2011Z169)安徽省高等学校省级优秀青年人才基金项目(2009SQRZ045) (2009SQRZ045)

A new compound 4-[(trans-(2-pyridyl))styryl]-N,N-dibutylbenzenamine has been synthesized and characterized by elemental analysis,UV,and X-ray single-crystal diffraction studies.The compound crystallizes in the triclinic system with space group P-1,a=1.15041(3) nm,b=1.45746(4) nm,c=1.51598(4) nm,Z=4,V=2.33068(11) nm³,R₁=0.0962,wR₂=0.2630.The result showed that the molecule with donor,π-conjugated bridge and acceptor(D-π-A) structure has good planarity,which results in effective electronic delocalization and increased intramolecular charge transfer.The molecules are linked by intermolecular C-H…π.It is believed that π electrons play a significant role for their packing,which attributed it with higher Stock shifts in photoluminescence properties.
- pyridine,
- D-π-A,
- opical properties,
- planarity
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