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Citation: FU Guiyun, YI Fei, SHENG Shouri, CAO Wei, LIU Xiaoling. Synthesis of Two Xthanene-Containing Bisphenols[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 974-976. doi: 10.3724/SP.J.1095.2011.00549 shu

Synthesis of Two Xthanene-Containing Bisphenols

1.
Institute of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022

Corresponding author: SHENG Shouri,
Received Date: 20 September 2010
Available Online: 5 November 2010
Fund Project: 国家自然科学基金(20664001)资助项目 (20664001)

Chlorination of xanthenone by thionyl chloride gave an intermediate 9,9-dichloroxanthene.The obtained chlorinated product is free of further isolation and purification and can react with o-cresol or 2,6-dimethylphenol for the preparation of two xthanenebiphenols including 9,9-bis(4-hydroxy-3-methylphenyl) xanthene and 9,9-bis(4-hydroxy-3,5-dimethylphenyl) xanthene with corresponding yields of 81% and 80.5%.Their structures were characterized by elemental analysis,FTIR,¹H NMR and ¹³C NMR spectra.The present method has advantages such as mild reaction conditions,convenient manipulation and good yield.
- xanthenone,
- dichloroxanthene,
- methyl-substituted phenol,
- bis (hydroxymethylphenyl) xanthene,
- bis (hydroxydimethylphenyl) xanthene,
- synthesis
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