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Citation: CHEN Xiaohua, GUO Jianping, CHEN Lin, TANG Binyan, YIN Dulin. Preparation and Modification of Poly(methyl methacrylate)-based Gel Polymer Electrolytes Containing [AMIM] BF₄[J]. Chinese Journal of Applied Chemistry, ;2011, 28(8): 869-873. doi: 10.3724/SP.J.1095.2011.00515 shu

Preparation and Modification of Poly(methyl methacrylate)-based Gel Polymer Electrolytes Containing [AMIM] BF₄

1.
College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

Corresponding author: GUO Jianping,
Received Date: 6 September 2010
Available Online: 8 November 2010
Fund Project: 湖南省科技计划项目(2006JT2009,2009FJ3052)资助 (2006JT2009,2009FJ3052)

A room temperature ionic liquid,1-allyl-3-methylimidazolium tetrafluoroborate([AMIM]BF₄) was prepared by a two-step synthesis.Then gel polymer electrolytes(GPE) prepared by incorporating the ionic liquid [AMIM]BF₄ and poly(methyl methacrylate)(PMMA) were modified with aprotic solvents propylene carbonate(PC) and dimethyl carbonate(DMC) and SiO₂ nano particles.The structure and properties of the GPE were studied by means of fourier transform infrared spectroscopy(FT-IR),A.C.impedance(AC),thermogravimetry(TG),and scanning electron microscope(SEM).The results showed that the introduction of aprotic solvents PC-DMC and nano-SiO₂ particles increased the ionic conductivity of the GPE,which showed a highly ionic conductivity of up to 5.25×10^-3 S/cm at room temperature.In addition,the conductive behavior of the GPE follows an Arrhenius equation.The gel polymer electrolytes shows high thermal stability and tends to decompose at temperature higher than 300℃.
- gel polymer electrolytes,
- ionic conductivity,
- ionic liquid,
- aprotic solvents,
- SiO₂ nano particles
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Preparation and Modification of Poly(methyl methacrylate)-based Gel Polymer Electrolytes Containing [AMIM] BF4

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通讯作者: 陈斌, bchen63@163.com

Preparation and Modification of Poly(methyl methacrylate)-based Gel Polymer Electrolytes Containing [AMIM] BF₄