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Citation: YANG Shengyan, WU Zhenyi. Synthesis and Photoelectric Property of the Bis (diphenylphosphino) Pentane-based Fullerene-platinum Complex[J]. Chinese Journal of Applied Chemistry, ;2011, 28(3): 272-277. doi: 10.3724/SP.J.1095.2011.00380 shu

Synthesis and Photoelectric Property of the Bis (diphenylphosphino) Pentane-based Fullerene-platinum Complex

YANG Shengyan ^a,b,, ,
WU Zhenyi ^b

1.
a Department of Chemistry and Material Science, Chaohu College, Chaohu 238000;
2.
b College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005

Corresponding author: YANG Shengyan,
Received Date: 29 June 2010
Available Online: 15 September 2010
Fund Project: 巢湖学院院级项目(XLY-201009)资助 (XLY-201009)

A fullerene-phosphine metal complex C₆₀Pt(dpppe) was synthesized by ligand substitution method with bis (diphenylphosphino) pentane and C₆₀ as ligand and platinum as central metal. The product was completely characterized by MS, elemental analysis, UV-Vis, IR and XPS. At the same time, the redox properties of the product were studied by cyclic voltammetry. The results showed that the reduction potential was negatively shifted after C₆₀ coordination with platinum. In addition, the energy level structure of the compound was determined by electronic spectrum, and energies of the highest occupied orbital and the lowest unoccupied orbital were 5.635 eV and 3.815 eV. In the meantime, the photovoltaic effect of the complex was determined in the photochemistry cell. The results showed that the fullerene-phosphine metal complex exhibited high photoelectric conversion property, especially under the conditions of BQ/H₂Q redox couples, and a maximum value of 358 mV was obtained for the photovoltage when the film thickness was 1~2 μm.
- fullerene,
- bis (diphenylphosphino) pentane,
- metal complexes,
- photoelectric effect
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