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Citation: QIU Jun, WANG Jiangang, SUN Jie. Synthesis of 1-Tetralones by Intramolecular Friedel-Crafts Reaction of 4-Phenylbutyric Acids Using Modified Zeolite H-BEA[J]. Chinese Journal of Applied Chemistry, ;2011, 28(2): 194-198. doi: 10.3724/SP.J.1095.2011.00367 shu

Synthesis of 1-Tetralones by Intramolecular Friedel-Crafts Reaction of 4-Phenylbutyric Acids Using Modified Zeolite H-BEA

1.
College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022

Corresponding author: QIU Jun,
Received Date: 25 June 2010
Available Online: 28 August 2010

Zeolite H-BEA modified by ethylene diamine tetraacetic acid(EDTA),citric acid,oxalic acid,and tartaric acid were prepared and characterized by XRD and NH₃-TPD.The catalytic performance was evaluated in the synthesis of 1-tetralone by intramolecular Friedel-Crafts reaction of 4-phenylbutyric acids.Zeolites H-BEA modified by citric acid showed high catalytic activity.In addition,the reaction conditions such as catalyst amount,reaction temperature and reaction time were examined for the optimal process conditions.Under the optimal reaction conditions,the yield for 1-tetralone was 94.3%.
- phenylbutyric acids,
- tetralones,
- intramolecular Friedel-Crafts,
- zeolites H-BEA
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