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Citation: MIAO Yingchun, ZHAI Zhongbiao, YANG Shengchun, WANG Jiaqiang. Catalytic Oxidation of 4-Methyl Pyridine to Isonicotinic Acid by H₂O₂ over Co-MCM-41[J]. Chinese Journal of Applied Chemistry, ;2011, 28(2): 188-193. doi: 10.3724/SP.J.1095.2011.00260 shu

Catalytic Oxidation of 4-Methyl Pyridine to Isonicotinic Acid by H₂O₂ over Co-MCM-41

1.
a Department of Chemistry and Chemical Engineering, Qujing Normal University, Qujing 655000;
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b Kunming Metallurgy Research Institute, Kunming;
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c Department of Applied Chemistry, Yunnan University, Kunming

Corresponding author: MIAO Yingchun,
Received Date: 5 May 2010
Available Online: 11 August 2010
Fund Project: 云南省教育厅科学研究基金(09Y0392) (09Y0392)曲靖师范学院科学研究基金(2009QN032) (2009QN032)曲靖师范学院应用电化学及材料制备研究创新团队(TD200901) (TD200901)

Liquid phase oxidation of 4-methylpyridine(4-MP) was carried out under mild reaction conditions over mesoporous Co-MCM-41 catalysts using aqueous hydrogen peroxide(30%) as oxidant and acetic acid as solvent without adding any initiator.The catalysts exhibited high substrate conversion and good product isonicotinic acid(4-PCA) selectivity.Recycling of the catalyst indicates that the catalyst can be used for a number of times without losing its activity significantly.The effects of solvent,reaction time,catalyst concentration,and reaction temperature on the catalyst performance were examined in order to optimize the conversion of 4-methylpyridine and the selectivity of isonicotinic acid.A 91.4% selectivity to isonicotinic acid was obtained at 96.5% conversion of 4-methylpyridine under the optimum reaction conditions:m(4-methyl pyridine):m(catalyst)=10:1,V(4-methyl pyridine):V(acetic acid glacial)=1:10,reaction temperature=363 K,reaction time=6 h.The reaction mechanism is proposed based on the results.
- Co-MCM-41,
- catalytic oxidation,
- methyl pyridine,
- isonicotinic acid
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Catalytic Oxidation of 4-Methyl Pyridine to Isonicotinic Acid by H₂O₂ over Co-MCM-41