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Citation: LI Xiaoping, LU Haiyan, REN Xiubin, LI Wei, DAN Yuanyuan, LIN Haibo. Preparation and Performances of PbO₂ Electrodes Doped with Fe or Co by the Electro-codeposition Method[J]. Chinese Journal of Applied Chemistry, ;2011, 28(5): 571-575. doi: 10.3724/SP.J.1095.2011.00182 shu

Preparation and Performances of PbO₂ Electrodes Doped with Fe or Co by the Electro-codeposition Method

LI Xiaoping ^a,b ,
LU Haiyan ^b,c,, ,
REN Xiubin ^b ,
LI Wei ^b ,
DAN Yuanyuan ^b ,
LIN Haibo ^b,c

1.
a Department of Chemistry, Baicheng Normal College, Baicheng;
2.
b College of Chemistry, Jilin University, Changchun 130012;
3.
c Suzhou Nistar Chemical Technology Co., Ltd, Suzhou 215123

Corresponding author: LU Haiyan,
Received Date: 31 March 2010
Available Online: 5 November 2010
Fund Project: 国家自然科学基金(20873051) (20873051)吉林省重点项目(20080306) (20080306)江苏省自然科学基金(BK2009596)资助项目 (BK2009596)

Ti/PbO₂ electrodes doped with Fe or Co were prepared by an electro-codeposition method.The effects of the Fe or Co on Ti/PbO₂ electrodes were investigated by the X-ray diffraction(XRD),scanning electron microscope(SEM) and cyclic voltammetry(CV).Compared with the pure Ti/PbO₂ electrode,the morphology of Ti/PbO₂ electrode doped with either Fe or Co remained nearly unchanged while their structures and performances were varied.The activities of oxygen evolution reaction(OER) were improved in Co doped electrode.The dissolution,re-deposition or crystalline transforming of PbO₂ took place during the electroreaction process.In addition,the lifetime of the electrodes might be influenced by such dissolution and re-deposition.
- anode,
- catalyst,
- oxides,
- electro-codeposition,
- PbO₂ electrodes
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Preparation and Performances of PbO₂ Electrodes Doped with Fe or Co by the Electro-codeposition Method