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Citation: HE Xiaohui, HE Fuping, NIE Huarong, CHEN Yiwang, WANG Kaiti. Synthesis and Addition Polymerization of 5-Butoxymethylenyl-2-norbornene[J]. Chinese Journal of Applied Chemistry, ;2011, 28(1): 10-15. doi: 10.3724/SP.J.1095.2011.00106 shu

Synthesis and Addition Polymerization of 5-Butoxymethylenyl-2-norbornene

1.
Institute of Polymers, Department of Chemistry, Nanchang University, Nanchang 330031

Corresponding author: CHEN Yiwang,
Received Date: 18 February 2010
Available Online: 14 April 2010
Fund Project: 国家自然科学基金(50663002) (50663002)江西省自然科学基金(2007GZC1727,2007GZH1704)资助项目 (2007GZC1727,2007GZH1704)

5-Butoxymethylenyl-2-norbornene (NBE-CH₂OC₄H₉) was synthesized. Polynorbornenes with functional groups were obtained by homo and copolymerizations of norbornene derivatives catalyzed by bis(β-ketonaphthylamino) Ni(Ⅱ)/B(C₆F₅)₃ system. Influences on polymerizations by changing polymerization time and copolymerization monomer feed ratios was examined. The catalytic bis(β-ketonaphthylamino) Ni(Ⅱ)/B(C₆F₅)₃ system exhibited higher catalysis activity. The obtained polymers were characterized by¹H NMR, FTIR and TGA. Results indicated that the incorporation rate could reach 22.1%~76.9% ether units at a molar fraction of 10%~90% of the NBE-CH₂ OC₄ H₉ in the monomer feed ratios; the polymerizations are confirmed to be vinyl-addition mode. The polymer has a good thermal stability(T_d >360℃) and is soluble in many common solvents, such as THF and CHCl₃.
- addition polymerization,
- butoxymethylenylnorbornene,
- polynorbornene,
- Ni complex
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