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Citation: PANG Shu-Feng, HUANG Rui-Fu, LV Xi-Juan. Assembling and Spectroscopy of Amphiphilic Azobenzene Derivatives in Cyclohexane[J]. Chinese Journal of Applied Chemistry, ;2010, 27(10): 1199-1203. doi: 10.3724/SP.J.1095.2010.90671 shu

Assembling and Spectroscopy of Amphiphilic Azobenzene Derivatives in Cyclohexane

Institute for Chemical Physics, School of Science, Beijing Institute of Technology, Beijing 100081

Received Date: 15 October 2009
Revised Date: 1 May 2010

A series of amphiphilic azobenzene derivatives were synthesized(including CH₃-Azo,COOH-Azo,CH₃O-Azo and SO₃H-Azo) and their aggregation behaviors were studied in cyclohexane.Transition electron microscope(TEM) observations revealed that hollow spherical,rod-like and tubular aggregations of CH₃OAzo,COOH-Azo and SO₃H-Azo,respectively,could be formed in the solvent.All four substituted azobenzenes show similar absorption bands around 350 nm in UV-Vis spectra and emit the same 625 nm fluorescence despite of the different natures of the four substitutes.The later might be ascribed to their aggregation behaviors.It is believed that the synergetic effect between the substitutes and hydrophobic chains among the supramolecular interactions in cyclohexane causes their morphological variations.
- aggregation,
- azobenzene,
- TEM,
- spectroscopy
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