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Citation: HU Ying-Mo. Synthesis and Characterization of Polymerizable Nonionic Surfactants[J]. Chinese Journal of Applied Chemistry, ;2010, 27(4): 409-412. doi: 10.3724/SP.J.1095.2010.90303 shu

Synthesis and Characterization of Polymerizable Nonionic Surfactants

HU Ying-Mo

School of Materials Science and Technology, China University of Geosciences, Beijing 100083

Received Date: 21 April 2009
Revised Date: 29 July 2009

Three polymerizable nonionic surfactants(Ⅱ-PEG400,Ⅱ-PEG1000,Ⅱ-PEG2000) were synthesized from 2,4-toluene dissocyanate(TDI),allyl alcohol and polyethylene glycol,and characterized by FT-IR.Results indicate that as the molecular mass of polyethylene glycol increases,the conductance is increased obviously,and the surface tension is decreased from 36.28 mN/m to 31.30 mN/m, while the cloud point is increased from 39.6℃ to 58.9℃.Their emulsifying abilities to BA,MMA and BMA are superior to that of OP-10,and the surfactants is homopolymerize or copolymerize with acrylate at 70℃ under the initiation of AIBN.
- polymerizable nonionic surfactant,
- conductance,
- surface tension,
- emulsifying ability
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