Citation: Wei-Guang YANG, Yu-Peng CAO, Hong-Bin JU, Ya-Kui WANG, Tao GENG, Ya-Jie JIANG. Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant[J]. Chinese Journal of Applied Chemistry, ;2021, 38(2): 220-227. doi: 10.19894/j.issn.1000-0518.200241 shu

Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant

China Research Institute of Daily Chemical Industry Co., Ltd, Taiyuan 030001, China

Corresponding author: Ya-Jie JIANG, jiangyajie2004@163.com
Received Date: 12 August 2020
Accepted Date: 15 October 2020

Fund Project: the National Key Research and Development Project of China 2017YFB0308900the Project of JALA Research Funds JALA 2018

Figures(6)

Oleamide quaternary ammonium Gemini surfactants GS-1, GS-2, GS-3 were synthesized by the reaction of Oleamide propyl dimethylamine and 1, 3-dichloro-2-propanol, 1, 4-dibromo-2-butene and 1, 4-dibromo-butane, respectively. The structures of GS-1, GS-2, and GS-3 were characterized by Fourier-transform infrared (FT-IR) spectrometry and proton nuclear magnetic resonance (¹H NMR), and their Krafft temperature, surface activity, emulsification performance, foam performance, and wettability were measured. The results show that three kinds of Gemini surfactants GS-1, GS-2, GS-3 are successfully prepared, and their Krafft temperatures are all less than 0℃, which provides a theoretical possibility for their use in low temperature environments with maintained high surface activity. Then, the critical micelle concentration (CMC) values of GS-1, GS-2, GS-3 are 7.7×10^-5, 7.08×10^-5, and 2.63×10^-6 mol/L, respectively, which are consistent with the expected results. The CMC value of the Gemini surfactant is 1~2 orders of magnitude lower than that of the conventional surfactant single alkyl chain. In addition, the synthesized surfactants all show good surface a ctivity, emulsifying properties, and the ability to stabilize foam.
- Gemini surfactant,
- Eco-friendly substances,
- Surface activity
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