Citation: Yun-Ting SHE, Chang-Yu YANG, De-Liang LI, Zhi-Xian CHANG. Reactive Extraction of Amphoteric Organics from the Dilute Solutions[J]. Chinese Journal of Applied Chemistry, ;2021, 38(1): 24-35. doi: 10.19894/j.issn.1000-0518.200150 shu

Reactive Extraction of Amphoteric Organics from the Dilute Solutions

Yun-Ting SHE ¹ ,
Chang-Yu YANG ¹ ,
De-Liang LI ^{1, 2,,} ,
Zhi-Xian CHANG ^{1, 3,,}

1.
Institute of Upconversion Nanoscale Materials, College of Chemistry and Chemical Engineering, Kaifeng 475004, China
2.
Research Center of Green Anticorrosion Technology for Magnesium Alloy in Henan Province, Kaifeng 475004, China
3.
Research Center of Heavy Metal Pollution Control and Restoration in Henan Province, Henan University, Kaifeng 475004, China

Corresponding author: De-Liang LI, lideliang@henu.edu.cn Zhi-Xian CHANG, chzx19@henu.edu.cn
Received Date: 19 May 2020
Accepted Date: 21 July 2020

Fund Project: the Key Program of the Higher Education Institutions of Henan Province 20A610004

Figures(5)

Reactive extraction has attracted great attentions and applications because the energy of its chemical bond is generally 10~60 kJ/mol, which not only facilitates the formation of complexes and phase transfer, but also makes the regeneration of complexing agent easier in the stripping process.This work summarizes the recent research progress on reactive extraction of amphoteric organics from the dilute solutions. The discussions mainly focus on the reactive extractions of various amphoteric organics, the kinetics of reactive extraction and new reactive extraction technique (i.e., flotation complexation extraction). In particular, the reactive extractions of amino acids, picolinic acid, hydroxypyridine, 4, 4 '-diaminostilbene-2, 2' -disulfonic acid, aminophenols, hydroxyquinoline and other commonly used amphoteric compounds are concluded. At last, the current research situation in this field is prospected. It points out that the weak industrial foundation and the lack of efficient green extractants are the main problems in the field, as well as some suggestions are put forward for the future research and industrial application.
- Reactive extraction,
- Dilution solution,
- Amphoteric organics,
- Kinetics,
- Flotation complexation extraction
1. [1]
  LI D L, LIU Q, CHANG Z X. Research progress on separation of polar organic dilute solution by complex extraction[J]. Chem Ind Eng Prog, 2009,28(1):13-18.
2. [2]
  BAI Y F, DING Y, ZHANG H Y. Research progress of separation and purification of amino acids[J]. Food Res Dev, 2007,28(2):175-178. doi: 10.3969/j.issn.1005-6521.2007.02.053
3. [3]
  BAI H H, GUO K X, CHEN X. Reactive extraction of L-valine with di(2-ethylhexyl) phosphate acid[J]. J Chem Technol Biotechnol, 2016,91:3096-3102. doi: 10.1002/jctb.5086
4. [4]
  BAI H H. Studies on reactive extraction of amino acid(amino acid-L-valine, L-alanine, glycine)[D]. Kaifeng: Henan University, 2015.
5. [5]
  FLORIAN B, MARTIN W. Efficient concentration of an amino acid using reactive extraction coupled with bipolar electrodialysis[J]. Chem Eng Technol, 2018,41(12):2298-2305. doi: 10.1002/ceat.201800286
6. [6]
  ZHANG J, ZHANG S X, YANG X N. Reactive extraction of amino acids mixture in hydrolysate from cottonseed meal with di(2-ethylhexyl) phosphoric acid[J]. J Chem Technol Biotechnol, 2016,91(2):483-489. doi: 10.1002/jctb.4602
7. [7]
  HUANG H F, RAJU N, MISUN C. Enantioselective liquid-liquid extractions of underivatized general amino acids with a chiral ketone extractant[J]. J Am Chem Soc, 2013,135(7):2653-2658. doi: 10.1021/ja3105945
8. [8]
  WANG W R, XU W F, DAI G L. Process optimization of reactive extraction of clorprenaline enantiomers by experiment and simulation[J]. Chem Eng Process, 2018,134:141-152. doi: 10.1016/j.cep.2018.10.021
9. [9]
  ZHANG P L, LUO J J, TANG K W. Kinetics study on reactive extraction of D-p-hydroxyphenylglycine by BINAP-palladium complex in Lewis cell[J]. Chem Eng Process, 2015,93:50-55. doi: 10.1016/j.cep.2015.04.007
10. [10]
  LIU J J, WU G H, TANG K W. Equilibrium of chiral extraction of 4-nitro-D, L-phenylalanine with BINAP metal complexes[J]. Chem Pap, 2014,68(1):80-89. doi: 10.2478%2Fs11696-013-0419-4
11. [11]
  TANG K W, WEN P, ZHANG P L. Fractional reactive extraction for symmetrical separation of 4-nitro-D, L-phenylalanine in centrifugal contactor separators: experiments and modeling[J]. Chirality, 2015,27(1):75-81. doi: 10.1002/chir.22392
12. [12]
  LIU X, YU M, CAO T. Enantioselective liquid-liquid extraction of amino acid enantiomers using (S)-MeO-BIPHEP-metal complexes as chiral extractants[J]. Sep Purif Technol, 2019,211:189-197. doi: 10.1016/j.seppur.2018.09.068
13. [13]
  LIU X, YU M, CAO T. Chiral extraction of amino acid enantiomers using (S)-SEGPHOS-metal complexes as extractants[J]. Chem Pap, 2020,74(4):1229-1239. doi: 10.1007/s11696-019-00970-z
14. [14]
  CHEN Q, JIN Y J, HUANG H F. Enantioselective liquid-liquid extraction of underivatized amino acids with simple chiral aminophenyl-aldehyde[J]. Bull Korean Chem Soc, 2018,39:960-964. doi: 10.1002/bkcs.11533
15. [15]
  CHULALAK N, NITI S, NOPPHAWA T. Synergistic enantioseparation of Rac-phenylalanine via hollow fiber supported liquid membrane[J]. Sep Sci Technol, 2013,48(6):867-876. doi: 10.1080/01496395.2012.719255
16. [16]
  LI H X, LI Z, YIN J M. Liquid-liquid extraction process of amino acids by a new amide-based functionalized ionic liquid[J]. Green Chem, 2012,14(6):1721-1727. doi: 10.1039/c2gc16560k
17. [17]
  LI D L, YU F, CHANG Z X. Reactive extraction of nicotinic acid with trialky-lamine in n-octanol[J]. Chinese J Chem Eng, 2012,20(5):843-848. doi: 10.1016/S1004-9541(12)60408-X
18. [18]
  YU F. Studies on reactive extraction of pyridine carboxylic acids using trialkylamine[D]. Kaifeng: Henan University, 2011.
19. [19]
  KUMAR S, WASEWAR K, BADU B V. Intensification of nicotinic acid separation using organophosphorous solvating extractants by reactive extraction[J]. Chem Eng Technol, 2008,31(11):1584-1590. doi: 10.1002/ceat.200800245
20. [20]
  KUMAR S, BADU B V. Extraction of pyridine-3-carboxylic acid using 1-dioctylphosphoryloctane (TOPO) with different diluents: equilibrium studies[J]. J Chem Eng Data, 2009,54(9):2669-2677. doi: 10.1021/je900205h
21. [21]
  DATTA D, KUMAR S, WASEWAR K L. Comparative study on reactive extraction of picolinic acid with six different extractants (phosphoric and aminic) in two different diluents (benzene and decan-1-ol)[J]. Sep Sci Technol, 2012,47(7):997-1005. doi: 10.1080/01496395.2011.638961
22. [22]
  DATTA D, USLU H, KUMAR S. Intensification of picolinic acid extraction with tri-n-butylphosphate and tri-n-octylamine in three different diluents[J]. Chem Eng Res Des, 2015,95:105-112. doi: 10.1016/j.cherd.2015.01.013
23. [23]
  DATTA D, KUMAR S. Reactive extraction of pyridine carboxylic acids with N, N-dioctyloctan-1-amine: experimental and theoretical studies[J]. Sep Sci Technol, 2013,48(6):898-908. doi: 10.1080/01496395.2012.712591
24. [24]
  DATTA D, KUMAR S. Equilibrium and kinetic studies of the reactive extraction of nicotinic acid with tri-n-octylamine dissolved in MIBK[J]. Ind Eng Chem Res, 2013,41(52):14680-14686.
25. [25]
  DATTA D, KUMAR S. Reactive extraction of picolinic acid using tri-n-octylamine dissolved in different diluents: effect of solvent polarity[J]. J Chem Eng Data, 2015,60(9):2709-2716. doi: 10.1021/acs.jced.5b00387
26. [26]
  TUYUN A F, USLU H. Extraction equilibria of picolinic acid from aqueous solution by tridodecylamine(TDA)[J]. Desalination, 2011,268(1/3):34-140.
27. [27]
  LI D L, CUI J H, CHANG Z X. Reactive extraction of iso-nicotinic acid with trialkylamine in different diluents[J]. J Chem Eng Data, 2009,54:795-800. doi: 10.1021/je8008914
28. [28]
  ZHANG L, YU F, CHANG Z X. Extraction equilibria of picolinic acid with trialkylamine/n-octanol[J]. J Chem Eng Data, 2012,57:577-581. doi: 10.1021/je201314m
29. [29]
  TUYUN A F, USLU H, GÖKMEN S. Recovery of picolinic acid from aqueous streams using a tertiary amine extractant[J]. J Chem Eng Data, 2011,56(5):2310-2315. doi: 10.1021/je1012923
30. [30]
  TUYUN A F, USLU H. Investigation of picolinic acid extraction by trioctylamine[J]. Int J Chem React Eng, 2011,9(1):1542-6580.
31. [31]
  TUYUN A F, USLU H. Extraction Equilibria of picolinic acid from aqueous solution by tridodecylamine(TDA)[J]. Desalination, 2011,268:134-140. doi: 10.1016/j.desal.2010.10.009
32. [32]
  WAGHMARE M D, WASEWAR K L, SONAWANE S S. Natural nontoxic solvents for recovery of picolinic acid by reactive extraction[J]. Ind Eng Chem Res, 2011,50(23):13526-13537. doi: 10.1021/ie201228u
33. [33]
  Waghmare M D, Wasewar K L, Sonawane S S. Reactive extraction of picolinic and nicotinic acid by natural non-toxic solvent[J]. Sep Purif Technol, 2013,120:296-303. doi: 10.1016/j.seppur.2013.10.019
34. [34]
  DATTA D, KUMAR S. Reactive extraction of pyridine-2-carboxylic acid (picolinic acid) using nontoxic extractant and diluent systems[J]. J Chem Eng Data, 2014,59(5):1540-1548. doi: 10.1021/je401110x
35. [35]
  DATTA D, BABU B V, KUMAR S. Equilibrium and thermodynamic studies on reactive extraction of nicotinic acid using a biocompatible extraction system[J]. J Chem Eng Data, 2017,62(10):3431-3436. doi: 10.1021/acs.jced.7b00457
36. [36]
  KUMARI A, GAUR A, WASEWAR K L. Modeling and optimization of reactive extraction of isonicotinic acid using tri-n-octylamine in biocompatible diluents mixture: response surface methodology and regeneration of solvents[J]. Ind Eng Chem Res, 2018,57(37):12485-12493. doi: 10.1021/acs.iecr.8b01533
37. [37]
  LI D L, ZHOU X F, CHANG Z X. Extraction of 8-hydroxyquinoline by tributylphosphate in kerosene[J]. J Chem Eng Data, 2012,57(10):2817-2822. doi: 10.1021/je300703z
38. [38]
  ZHOU X F. Studies on reactive extraction of hydroxypyridine using di-(2-ethylhexyl)phosphoric acid[D]. Kaifeng: Henan University, 2012.
39. [39]
  GALACTION A I, CAMARUT M, CASCAVAL D. Separation of p-aminobenzoic acid by reactive extraction 1. mechanism and influencing factors[J]. Chem Ind Chem Eng Q, 2008,14(3):159-165. doi: 10.2298/CICEQ0803159G
40. [40]
  GALACTION A I, CASCAVAL D. Comparative Study on separation of p-aminobenzoic and p-hydroxybenzoic acids by reactive extraction[J]. Rev Med Chir Soc Med Nat Iasi, 2008,112(4):1110-1114.
41. [41]
  GALACTION A I, KLOETZER L, CASCAVAL D. Separation of p-aminobenzoic acid by reactive extraction in the presence of 1-octanol as phase modifier[J]. Chem Biochem Eng Q, 2010,24(2):149-157.
42. [42]
  CASCAVAL D, GALACTION A I, KLOETZER L. Mathematical modeling of p-aminobenzoic acid reactive extraction without and with phase modifier[J]. Rom Biotechnol Lett, 2010,15(2):5146-5153.
43. [43]
  YU L, WU S Z. Study on DSD acid wastewater treatment with continuous complex extraction method[J]. Environ Eng, 2013,31(4):59-62.
44. [44]
  GAO F. Treatment of oxidation wastewater in DSD acid production by extraction Method[J]. Environ Prot Chem Ind, 2015,35(3):300-304. doi: 10.3969/j.issn.1006-1878.2015.03.016
45. [45]
  CUI J H, DU X H, ZHENG B G. Study on complexation extraction mechanism of o-aminophenol[J]. Chinese J Spectrosc Lab, 2009,26(2):177-181. doi: 10.3969/j.issn.1004-8138.2009.02.002
46. [46]
  CUI J H, CUI J R, ZHENG B H. Study on complexation extraction structure of o-aminophenol by FTIR[J]. Chinese J Spectrosc Lab, 2009,26(3):515-518. doi: 10.3969/j.issn.1004-8138.2009.03.015
47. [47]
  CUI J H, LI C G, DU X H. Reactive extraction of o-aminophenol with tri-n-butyl phosphate in different solvents[J]. J Chem Eng Data, 2011,56(7):3149-3156. doi: 10.1021/je200219m
48. [48]
  CHANG Z X, XU M, ZHANG L. Reactive extraction of o-, m-, and p-aminophenol using trialkylphosphine oxide/kerosene[J]. J Chem Eng Data, 2012,57(7):2030-2036. doi: 10.1021/je300329h
49. [49]
  LI D L, GUO Y Y, CHANG Z X. Extraction of 8-hydroxyquinoline by tributylphosphate in kerosene[J]. J Chem Eng Data, 2012,57(10):2817-2822. doi: 10.1021/je300703z
50. [50]
  GUO Y Y. Studies on reactive extraction of hydroxyquinoline in dilute solution[D]. Kaifeng: Henan University, 2013.
51. [51]
  GONG J C. The research of reactive extraction on three kinds of hydroxyquionline dilute solution[D]. Kaifeng: Henan University, 2016.
52. [52]
  ZHANG Nan. Study on recovering process of 7-ACA in pharmaceutical wastewater by hollow fiber supported liquid membrane[D]. Tianjin: Tianjin University, 2016.
53. [53]
  ZENG R, CHEN J, WANG S. Recovery of 6-APA from waste liquid by reactive extraction[J]. Mod Chem Ind, 2015,35(10):125-129.
54. [54]
  ZHOU B Q. The study on processing of the low concentration 6-aminopenicillanic solution acid by liquid membrane[D]. Tianjin: Tianjin University, 2015
55. [55]
  GALACTION A I, POSTARU M, TUCALIUC A. Reactive extraction of 6-aminopenicillanic acid[J]. New Biotechnol, 2018,44SS138.
56. [56]
  GAI H J, ZHONG C Y, QIAO L. Extraction of 1-amino-2-naphthol-4-sulfonic acid from wastewater using trioctylamine (N, N-dioctyloctan-1-amine) in methyl isobutyl ketone[J]. J Clean Prod, 2018,201:774-782. doi: 10.1016/j.jclepro.2018.08.082
57. [57]
  TANG K W, LUO J J, ZHANG P L. Kinetic study on reactive extraction of phenylalanine enantiomers with BINAP-copper complexes[J]. Chinese J Chem Eng, 2015,23(1):57-63. doi: 10.1016/j.cjche.2014.01.001
58. [58]
  TANG K W, XIE N, CHEN X M. Kinetics study on the reactive extraction of homophenylalanine enantiomers with BINAP-copper complex[J]. Sep Sci Technol, 2016,51(12):1994-2000. doi: 10.1080/01496395.2016.1200084
59. [59]
  ZIMMERMANN V, MASUCK I, KRAGL U. Reactive extraction of N-acetylneuraminic acid-kinetic model and simulation of integrated product removal[J]. Sep Purif Technol, 2008,63:129-137. doi: 10.1016/j.seppur.2008.04.005
60. [60]
  BI PY, DONG H R, YU H B. Separation and enrichment of L-phenylalanine by air flotation complexation extraction[J]. Chinese J Anal Chem, 2008,36(5):658-662. doi: 10.3321/j.issn:0253-3820.2008.05.019
61. [61]
  BI P Y, DONG H R, YU H B. A new technique for separation and purification of L-phenylalanine from fermentation liquid: flotation complexation extraction[J]. Sep Purif Technol, 2008,63:487-491. doi: 10.1016/j.seppur.2008.06.016
62. [62]
  YU H B, DONG H R, BI Y P. Air flotation complex extraction of L-tryptophan and its separation mechanism[J]. J Univ Sci Technol B, 2011,38(1):40-43.
63. [63]
  YU H B. Application of floatation complexation extraction on separation and concentration of organics with amphoteric functional groups, and the study on the separation mechanism[D]. Beijing: Beijing University of Chemical Technology, 2011.
64. [64]
  LIANG B, WU Z L, HU B. Separation of arginine by foam flotation[J]. Mod Chem Ind, 2008,28(7):43-46. doi: 10.3321/j.issn:0253-4320.2008.07.010
65. [65]
  LIANG B, WU Z L, HU B. The technology of solvent flotation separation of arginine and its separation mechanism[J]. Chinese J Anal Chem, 2009,37(7):980-984. doi: 10.3321/j.issn:0253-3820.2009.07.008
66. [66]
  WU Z L, LIANG B, HU B. Separation of L-lysine by solvent sublation[J]. Sep Purif Technol, 2009,66:237-241. doi: 10.1016/j.seppur.2009.01.006
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