Citation: WANG Cui, BAI Li-Peng, SONG Pan-Pan, GAI Pan-Pan, LI Feng. Ratiometric Colorimetry Sensor for Paraoxon Detection Based on Dual-Nanozyme Activity of Cerium Oxide[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(6): 954-961. doi: 10.19756/j.issn.0253-3820.231079 shu

Ratiometric Colorimetry Sensor for Paraoxon Detection Based on Dual-Nanozyme Activity of Cerium Oxide

College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China

Corresponding author: GAI Pan-Pan, LI Feng,
Received Date: 3 March 2023
Revised Date: 23 March 2023

Fund Project: Cerium oxide

A ratiometric colorimetric sensor for sensitive detection of paraoxon was constructed based on the organophosphorus hydrolase-like activity and oxidase-like activity of cerium oxide nanoparticles (CeO₂ NPs). The CeO₂ NPs with OPH-like activity catalyzed hydrolysis of paraoxon to generate yellow p-nitrophenol, which had an obvious absorption peak at 400 nm. At the same time, CeO₂ NPs featured with oxidase-like activity could catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) into a blue oxidation state TMB, which had a significant absorption peak at 653 nm. In the presence of paraoxon, CeO₂ nanozyme hydrolyzed paraoxon to p-nitrophenol, and the absorbance value of the system at 400 nm (A₄₀₀) increased. Meanwhile, paraoxon inhibited the oxidase-like activity of CeO₂ nanozyme, and the absorbance value of the TMB system at 653 nm (A₆₅₃) decreased. The sensitive and accurate detection of paraoxon was realized based on the changes of A₄₀₀/A₆₅₃ before and after the addition of paraoxon, and the detection limit was 0.03 μmol/L (S/N=3). This method was used to detect the content of paraoxon in Chinese chives samples, and the recoveries were 92.0%-99.2%. This work developed a ratiometric colorimetric sensing method based on the dual-nanozyme activity of CeO₂ NPs, providing a new strategy for the sensitive detection of paraoxon residues in food.
- Supported by the National Natural Science Foundation of China (Nos. 22274086, 22076090).,
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