Citation: ZHANG Di, ZHANG Hai-Yan, CHEN Bo-Xin, ZHU Yu-Chen, ZHAO Bin, LI Lei, ZHENG Dan, FENG Fei. Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(3): 429-435. doi: 10.19756/j.issn.0253-3820.221492 shu

Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase

ZHANG Di ^1,2 ,
ZHANG Hai-Yan ^1,2 ,
CHEN Bo-Xin ² ,
ZHU Yu-Chen ² ,
ZHAO Bin ² ,
LI Lei ² ,
ZHENG Dan ^1,, ,
FENG Fei ^2,,

1.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
2.
State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: ZHENG Dan, FENG Fei,
Received Date: 4 October 2022
Revised Date: 24 November 2022

Fund Project: Supported by the National Key R&D Program of China (Nos. 2018YFA0208504, 2021YFC2800301), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDA22020504) and the Shanghai Science and Technology Innovation Action Plan, Medical Innovation Research Special Project (No. 22Y11900600).

The miniaturization of gas chromatographic columns is beneficial to the miniaturization of gas chromatographic systems. The separation of light alkanes is a challenge for micro gas chromatographic columns (μGCC). Metal organic framework material is a new type of porous material that has been developed rapidly in the last two decades, and has attracted a lot of attention from researchers as stationary phases for gas chromatography. In this study, a μGCC was prepared based on MEMS technology, and a metal organic framework material HKUST-1 was synthesized at room temperature. HKUST-1 was coated into the μGCC as a stationary phase by dynamic coating method. The testing result of the μGCC with HKUST-1 stationary phase showed that the μGCC could completely separate light alkanes mixtures (methane, ethane, propane and n-butane), and the resolution of methane and ethane that were difficult to separate was 9.2.
- Micro gas chromatographic column,
- Metal organic framework material,
- HKUST-1,
- Separation of Light alkanes
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